Formation of partially ordered organic planar systems based on the in situ control of their structural organization


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Abstract

The possibilities of significantly improving the quality of planar systems based on photoactive porphyrin–fullerene dyads, layers based on cytochrome c and cardiolipin, and lysozyme crystals and films using a complex of in situ X-ray methods and simulation are described. The potential of X-ray phase-sensitive and surface-sensitive methods developed by M.V. Koval’chuk and researchers from his school in monitoring all stages of synthesis of partially ordered organic structure is demonstrated. This approach shows its efficiency for in situ studies: starting from the formation of complexes in solutions up to the growth of protein films and crystals.

About the authors

Yu. A. Dyakova

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”; National Research Centre “Kurchatov Institute,”

Author for correspondence.
Email: juliaadi@gmail.com
Russian Federation, Leninskii pr. 59, Moscow, 119333; pl. Akademika Kurchatova 1, Moscow, 123182

M. A. Marchenkova

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”; National Research Centre “Kurchatov Institute,”

Email: juliaadi@gmail.com
Russian Federation, Leninskii pr. 59, Moscow, 119333; pl. Akademika Kurchatova 1, Moscow, 123182

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