Email this article Synthesis and the crystal and molecular structure of the Sn(IV)–Nd(III) coordination polymer based on the tartaric acid [NdSn2{H(Tart)3} · 12H2O]n
- Authors: Sergienko V.S.1, Chebanenko E.A.2, Seifullina I.I.2, Churakov A.V.1, Martsinko E.E.2
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Mechnikov Odessa National University
- Issue: Vol 61, No 2 (2016)
- Pages: 209-215
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/189820
- DOI: https://doi.org/10.1134/S1063774516020206
- ID: 189820
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Abstract
The polymeric heterometallic [NdSn2{H(Tart)3} ∙ 12H2O]n (I) compound, where H4Tart is the tartaric acid, is synthesized and characterized by elemental analysis, X-ray diffraction, thermogravimetry, and IR spectroscopy. The structural elements of crystal I, namely, polymeric [{Nd(H2O)6}(μ3-HnTart4–n) {Sn(μ2-HnTart4–n)}2} (n = 0, 1) complex molecules and crystallization water molecules, are connected by an extended hydrogen-bond system.
About the authors
V. S. Sergienko
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: sergienko@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
E. A. Chebanenko
Mechnikov Odessa National University
Email: sergienko@igic.ras.ru
Ukraine, ul. Dvoryanskaya 2, Odessa, 65082
I. I. Seifullina
Mechnikov Odessa National University
Email: sergienko@igic.ras.ru
Ukraine, ul. Dvoryanskaya 2, Odessa, 65082
A. V. Churakov
Kurnakov Institute of General and Inorganic Chemistry
Email: sergienko@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
E. E. Martsinko
Mechnikov Odessa National University
Email: sergienko@igic.ras.ru
Ukraine, ul. Dvoryanskaya 2, Odessa, 65082
