Email this article Spectral Distortions of Metalloporphyrin Forms at Low Temperatures
- Authors: Starukhin A.S.1, Gorski A.V.2, Kijak M.Z.2
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Affiliations:
- Stepanov Institute of Physics, National Academy of Sciences of Belarus
- Institute of Physical Chemistry, Polish Academy of Sciences
- Issue: Vol 82, No 12 (2018)
- Pages: 1560-1564
- Section: Article
- URL: https://journals.rcsi.science/1062-8738/article/view/186964
- DOI: https://doi.org/10.3103/S1062873818120225
- ID: 186964
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Abstract
The planar form and two types of distorted molecular conformations in the ground electronic state for a number of metalloporphyrins in solid matrices exist simultaneously. A comparison of experimental data and results from quantum chemical calculations is discussed in order to analyze the structure of distorted porphyrin macrocycles at cryogenic temperatures.
About the authors
A. S. Starukhin
Stepanov Institute of Physics, National Academy of Sciences of Belarus
Author for correspondence.
Email: a.starukhin@ifanbel.bas-net.by
Belarus, Minsk, 220072
A. V. Gorski
Institute of Physical Chemistry, Polish Academy of Sciences
Email: a.starukhin@ifanbel.bas-net.by
Poland, Warsaw, 01-224
M. Z. Kijak
Institute of Physical Chemistry, Polish Academy of Sciences
Email: a.starukhin@ifanbel.bas-net.by
Poland, Warsaw, 01-224
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