Spectral Distortions of Metalloporphyrin Forms at Low Temperatures


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The planar form and two types of distorted molecular conformations in the ground electronic state for a number of metalloporphyrins in solid matrices exist simultaneously. A comparison of experimental data and results from quantum chemical calculations is discussed in order to analyze the structure of distorted porphyrin macrocycles at cryogenic temperatures.

作者简介

A. Starukhin

Stepanov Institute of Physics, National Academy of Sciences of Belarus

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Email: a.starukhin@ifanbel.bas-net.by
白俄罗斯, Minsk, 220072

A. Gorski

Institute of Physical Chemistry, Polish Academy of Sciences

Email: a.starukhin@ifanbel.bas-net.by
波兰, Warsaw, 01-224

M. Kijak

Institute of Physical Chemistry, Polish Academy of Sciences

Email: a.starukhin@ifanbel.bas-net.by
波兰, Warsaw, 01-224

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