In situ Raman spectroscopic study of interaction between phengite and water under PT conditions typical of subduction zones


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Abstract

In situ Raman spectroscopy is used to study the layered mineral phengite K(Al, Mg)2(Si, Al)4O10(OH)2 in water under the high temperature and pressure conditions typical of cold subduction zones (T up to 373°C and P = 12.5 GPa). High pressure and temperature were created in a resistively heated diamond anvil cell. Raman spectra show the high PT stability of phengite. No reversible polymorphic transitions (overhydration or notable amorphization) are observed.

About the authors

S. V. Goryainov

Sobolev Institute of Geology and Mineralogy

Author for correspondence.
Email: svg@igm.nsc.ru
Russian Federation, Novosibirsk, 630090

A. S. Krylov

Kirensky Institute of Physics

Email: svg@igm.nsc.ru
Russian Federation, Akademgorodok, Krasnoyarsk, 660036

O. P. Polyansky

Sobolev Institute of Geology and Mineralogy

Email: svg@igm.nsc.ru
Russian Federation, Novosibirsk, 630090

A. N. Vtyurin

Kirensky Institute of Physics

Email: svg@igm.nsc.ru
Russian Federation, Akademgorodok, Krasnoyarsk, 660036

N. Yu. Zmeeva

Ural State University of Economics

Email: svg@igm.nsc.ru
Russian Federation, Yekaterinburg, 620219

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