Extraction of Scandium Nitrate and Thiocyanate Complexes Using Two-Phase Aqueous Systems and the Determination of Scandium
- 作者: Simonova T.1, Fedotov A.1, Alemasova N.2
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隶属关系:
- Faculty of Chemistry
- Litvinenko Institute of Physical Organic and Coal Chemistry
- 期: 卷 73, 编号 1 (2018)
- 页面: 18-22
- 栏目: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/182946
- DOI: https://doi.org/10.1134/S1061934818010112
- ID: 182946
如何引用文章
详细
Two-phase aqueous systems, polyethylene glycol PEG-3000 (C3H7OH)–NaNO3 (NaNO3 + KSCN)–H2O, are proposed for the selective extraction of scandium nitrate and thiocyanate complexes followed by the complexometric and spectrophotometric determination of scandium. Conditions for analyte separation from rare-earth and concomitant elements are optimized. The procedures are tested on samples of rare-earth metals, concentrates, and an aluminum alloy. The relative standard deviation is not more than 0.8% for complexometric determination and 4.6% for spectrophotometric determination. The time of analysis is not longer than 30 min.
作者简介
T. Simonova
Faculty of Chemistry
编辑信件的主要联系方式.
Email: simonovatn@yandex.ru
乌克兰, Donetsk, 83001
A. Fedotov
Faculty of Chemistry
Email: simonovatn@yandex.ru
乌克兰, Donetsk, 83001
N. Alemasova
Litvinenko Institute of Physical Organic and Coal Chemistry
Email: simonovatn@yandex.ru
乌克兰, Donetsk, 83114