Prediction of electron ionization mass spectra of О-alkyl methylphosphonothionofluoridates
- 作者: Morozik Y.1,2, Dudkin A.2, Tkachuk Y.2, Rybal’chenko I.1, Khatymov R.3
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隶属关系:
- Kostroma State Technological University
- Military Academy of Nuclear, Biological and Chemical Defense
- Institute of Molecule and Crystal Physics, Ufa Research Center
- 期: 卷 71, 编号 14 (2016)
- 页面: 1319-1325
- 栏目: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/182236
- DOI: https://doi.org/10.1134/S1061934816140100
- ID: 182236
如何引用文章
详细
Electron ionization mass spectra of poorly studied toxic alkyl methylphosphonothionofluoridates and alkyl methylphosphonofluoridates are discussed. It is demonstrated that the compounds are decomposed in accordance with the general scheme of fragmentation of monofunctional organic compounds RX (X is a functional group), proposed previously. At the same time, noticeable differences between the corresponding mass spectra are found. The most important difference occurs in their alkene subspectra containing a peak of alkene ion [R–H]+• and peaks of its decay products. A method was developed for the simulation of mass spectra of unknown alkyl methylphosphonothionofluoridates by transforming available mass spectra of their oxygen analogues.
作者简介
Yu. Morozik
Kostroma State Technological University; Military Academy of Nuclear, Biological and Chemical Defense
Email: AleksVDud@gmail.com
俄罗斯联邦, Kostroma, 156001; Kostroma, 156015
A. Dudkin
Military Academy of Nuclear, Biological and Chemical Defense
编辑信件的主要联系方式.
Email: AleksVDud@gmail.com
俄罗斯联邦, Kostroma, 156015
Yu. Tkachuk
Military Academy of Nuclear, Biological and Chemical Defense
Email: AleksVDud@gmail.com
俄罗斯联邦, Kostroma, 156015
I. Rybal’chenko
Kostroma State Technological University
Email: AleksVDud@gmail.com
俄罗斯联邦, Kostroma, 156001
R. Khatymov
Institute of Molecule and Crystal Physics, Ufa Research Center
Email: AleksVDud@gmail.com
俄罗斯联邦, Ufa, Bashkortostan, 450075