Molar absorption coefficient of ozone in aqueous solutions
- Autores: Levanov A.1, Isaikina O.2, Tyutyunnik A.1, Antipenko E.1, Lunin V.1,2
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Afiliações:
- Department of Chemistry
- Topchiev Institute of Petrochemical Synthesis
- Edição: Volume 71, Nº 6 (2016)
- Páginas: 549-553
- Seção: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/181750
- DOI: https://doi.org/10.1134/S1061934816060083
- ID: 181750
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Resumo
The value of the molar absorption coefficient of ozone in aqueous solutions (2992 ± 71 M–1 cm–1 at 260 nm) is found based on the determination of ozone concentration by iodometry. This value is confirmed by the results of determination of O3 concentration by reaction with the bromide ion and virtually coincides with the maximum absorption coefficient of ozone in the gas phase in the region the Hartley band. In the determinations of ozone concentration in aqueous solutions by direct spectrophotometry, we recommend the value of the molar absorption coefficient ε(О3)260 = 3000 M–1 cm–1.
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Sobre autores
A. Levanov
Department of Chemistry
Autor responsável pela correspondência
Email: levanov@kge.msu.ru
Rússia, Moscow, 119991
O. Isaikina
Topchiev Institute of Petrochemical Synthesis
Email: levanov@kge.msu.ru
Rússia, Leninskii pr. 29, Moscow, 119991
A. Tyutyunnik
Department of Chemistry
Email: levanov@kge.msu.ru
Rússia, Moscow, 119991
E. Antipenko
Department of Chemistry
Email: levanov@kge.msu.ru
Rússia, Moscow, 119991
V. Lunin
Department of Chemistry; Topchiev Institute of Petrochemical Synthesis
Email: levanov@kge.msu.ru
Rússia, Moscow, 119991; Leninskii pr. 29, Moscow, 119991