Group Identification of O-Alkyl Alkylphosphonothionofluoridates by Electron Ionization Mass Spectra Using Generalized Spectral Images of Taxonomic Groups
- Авторлар: Morozik Y.1,2, Dudkin A.2, Rybal’chenko I.1, Naumov A.1
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Мекемелер:
- Kostroma State University
- Military Academy of Nuclear, Biological, and Chemical Defense
- Шығарылым: Том 73, № 13 (2018)
- Беттер: 1253-1259
- Бөлім: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/182907
- DOI: https://doi.org/10.1134/S1061934818130117
- ID: 182907
Дәйексөз келтіру
Аннотация
A method is proposed for the group identification of poorly studied highly toxic O-alkyl alkylphosphonothionofluoridates by electron ionization mass spectra. The method is based on the use of generalized spectral images of four taxonomic groups of this class, subjected to control under the Chemical Weapon Convention. The generalized spectral images were obtained by analyzing the revealed regularities of the fragmentation of these compounds. An advantage of the proposed method is that the assignment of a test substance to one of the class groups and to a class as a whole is a rapid automated standard procedure used in the NIST information retrieval system.
Авторлар туралы
Yu. Morozik
Kostroma State University; Military Academy of Nuclear, Biological, and Chemical Defense
Email: AleksVDud@gmail.com
Ресей, Kostroma, 156001; Kostroma, 156015
A. Dudkin
Military Academy of Nuclear, Biological, and Chemical Defense
Хат алмасуға жауапты Автор.
Email: AleksVDud@gmail.com
Ресей, Kostroma, 156015
I. Rybal’chenko
Kostroma State University
Email: AleksVDud@gmail.com
Ресей, Kostroma, 156001
A. Naumov
Kostroma State University
Email: AleksVDud@gmail.com
Ресей, Kostroma, 156001