Application of Silica Chemically Modified by Sulfur-Containing Groups to the Separation and Determination of Platinum and Rhenium in Catalysts Based on Aluminum Oxide
- Authors: Losev V.N.1, Parfenova V.V.1, Elsuf’ev E.V.1, Buiko O.V.1, Didukh S.L.1, Belousov O.V.2, Maksimov N.G.2
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Affiliations:
- Research and Engineering Center Kristall
- Institute of Chemistry and Chemical Technology, Siberian Branch
- Issue: Vol 73, No 4 (2018)
- Pages: 325-333
- Section: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/182995
- DOI: https://doi.org/10.1134/S106193481804007X
- ID: 182995
Cite item
Abstract
Adsorbents based on silica chemically modified by sulfur-containing groups (dithiocarbamate, thiodiazolethiol, mercaptophenyl, and aminobenzothiazole) quantitatively extract (recovery ≥99%) platinum( IV) from solutions ranging from 4 M HCl to pH 6. Under the conditions of the adsorption separation of platinum(IV), rhenium(VII) is not extracted and remains in the solution. The subsequent quantitative (98–99%) adsorption of rhenium(VII) is achieved in the presence of a 1000-fold excess of tin(II) chloride. Adsorption on the surface of adsorbents leads to the formation of platinum(II) complexes with sulfur-containing groups, luminescent at 77 K on irradiation with UV light. The luminescence spectra of surface platinum( II) complexes are located in the region of 550–700 nm. In the adsorption of rhenium(III) in the presence of tin(II) chloride, intensely colored brown complexes of rhenium formed on the surface of adsorbents. Electron paramagnetic resonance showed that, in the surface complexes, rhenium is in the oxidation state 2+. Silicas chemically modified by sulfur-containing groups were used in the development of procedures for the sequential isolation and determination of platinum and rhenium in solutions after the decomposition of aluminum–platinum–rhenium catalysts.
About the authors
V. N. Losev
Research and Engineering Center Kristall
Author for correspondence.
Email: losevvn@gmail.com
Russian Federation, Krasnoyarsk, 660041
V. V. Parfenova
Research and Engineering Center Kristall
Email: losevvn@gmail.com
Russian Federation, Krasnoyarsk, 660041
E. V. Elsuf’ev
Research and Engineering Center Kristall
Email: losevvn@gmail.com
Russian Federation, Krasnoyarsk, 660041
O. V. Buiko
Research and Engineering Center Kristall
Email: losevvn@gmail.com
Russian Federation, Krasnoyarsk, 660041
S. L. Didukh
Research and Engineering Center Kristall
Email: losevvn@gmail.com
Russian Federation, Krasnoyarsk, 660041
O. V. Belousov
Institute of Chemistry and Chemical Technology, Siberian Branch
Email: losevvn@gmail.com
Russian Federation, Krasnoyarsk, 660075
N. G. Maksimov
Institute of Chemistry and Chemical Technology, Siberian Branch
Email: losevvn@gmail.com
Russian Federation, Krasnoyarsk, 660075