An enantioselective voltammetric sensor for the recognition of propranolol stereoisomers
- Authors: Sidel’nikov A.V.1, Maistrenko V.N.1, Zil’berg R.A.1, Yarkaeva Y.A.1, Khamitov E.M.1
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Affiliations:
- Department of Chemistry
- Issue: Vol 72, No 5 (2017)
- Pages: 575-581
- Section: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/182467
- DOI: https://doi.org/10.1134/S1061934817050112
- ID: 182467
Cite item
Abstract
An enantioselective voltammetric sensor for the recognition of propranolol stereoisomers is developed based on a carbon-paste electrode modified with uracil supramolecular structures and the use of chemometric methods. The conditions for the formation of an enantioselective selector on the surface of graphite (graphene) particles and the selective registration of voltammograms of enantiomers, as well as the possibility of the recognition thereof, are studied by methods of molecular dynamics simulation and voltammetry.
About the authors
A. V. Sidel’nikov
Department of Chemistry
Email: ZilbergRA@yandex.ru
Russian Federation, Ufa, 450076
V. N. Maistrenko
Department of Chemistry
Email: ZilbergRA@yandex.ru
Russian Federation, Ufa, 450076
R. A. Zil’berg
Department of Chemistry
Author for correspondence.
Email: ZilbergRA@yandex.ru
Russian Federation, Ufa, 450076
Yu. A. Yarkaeva
Department of Chemistry
Email: ZilbergRA@yandex.ru
Russian Federation, Ufa, 450076
E. M. Khamitov
Department of Chemistry
Email: ZilbergRA@yandex.ru
Russian Federation, Ufa, 450076