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Vol 30, No 4 (2017)

Spectroscopy of Ambient Medium

Radiative transfer code for the thermal and near-infrared regions with multiple scattering

Zadvornykh I.V., Gribanov K.G., Zakharov V.I., Imasu R.

Abstract

FIRE-ARMS software was supplemented with the vector radiative transfer model VLIDORT. The new version of the software allows simulating outgoing thermal infrared radiation (TIR) from the Earth and solar shortwave infrared radiation (SWIR) reflected from the surface taking into account multiple scattering for the same atmospheric model and sensing geometry. We performed simulations of the spectra of outgoing TIR and SWIR radiation with multiple scattering in a cloudless atmosphere and compared them with the spectra measured by GOSAT satellite spectrometers in the cloudless atmosphere over Western Siberia. Analysis of calculated weighting functions shows that simultaneous use of the TIR and SWIR spectral regions will improve the height resolution in vertical profiling of methane concentrations in the atmosphere.

Atmospheric and Oceanic Optics. 2017;30(4):305-310
pages 305-310 views

Collisional self-broadening coefficients and probabilities of spontaneous emission of the CO2 1000–0001 transition lines

Arshinov K.I., Krapivnaya O.N., Nevdakh V.V.

Abstract

Using a tunable frequency-stabilized CO2 laser, the pressure dependences of unsaturated absorption coefficients (AC) are measured in pure carbon dioxide in the pressure range from 5 to 30 Torr, where the spectral line shape is described by the Voigt profile. The absorption coefficients are measured in the centers of R(8), R(22), R(34), P(22), and P(36) spectral lines of the 1000–0001 transition in the temperature range 300–700 K. By means of the least-squares method, the inverse problem is solved for the system of equations for AC at different pressures in the temperature range under study. The self-broadening coefficients \({\gamma _{C{O_2} - C{O_2}}}\) and the probabilities of spontaneous emission Aik are derived. A new formula is proposed for \({\gamma _{C{O_2} - C{O_2}}}\) (T) dependence.

Atmospheric and Oceanic Optics. 2017;30(4):311-315
pages 311-315 views

Resonance functions in the theory of collisional broadening of molecule spectral lines at low temperatures

Starikov V.I.

Abstract

Eleven resonance functions are calculated in the exact trajectory model, which can be used for calculation of broadening coefficients γ of molecular lines during interactions with atoms of inert gases at very low temperatures. These functions correspond to the atom-atom potential and the potential V(R, θ) written in terms of Legendre polynomials. The functions are represented in analytical form. The broadening coefficients γ are calculated for absorption lines of CO perturbed by He and Ar at temperatures T from 300 to 2 K using the potential V(R, θ). It is shown that the dependence γ(T) for low temperatures T is determined by the potential well depth. For the CO–He system, a comparison with the experimental data is performed.

Atmospheric and Oceanic Optics. 2017;30(4):316-323
pages 316-323 views

Optics of Clusters, Aerosols, and Hydrosoles

Optimization of optical radiation absorption by multilayer spherical microparticles

Geints Y.E., Panina E.K., Zemlyanov A.A.

Abstract

The spatial distribution and amplitude characteristics of the power absorbed inside multilayer particle-microcapsules, which consist of a liquid core and one or more polymer shells, is studied during changing the thickness and refractive index of the external shell; the position of the field localization is determined. This problem is important for the solution of practical tasks associated with opening the microcapsule shells in the appropriate spatial areas.

Atmospheric and Oceanic Optics. 2017;30(4):324-330
pages 324-330 views

Nonlinear Optics

Kerr nonlinearity effect on femtosecond pulse radiation filamentation in air

Ivanov N.G., Losev V.F.

Abstract

The conditions for filamentation of femtosecond pulse laser radiation when focusing in air are studied experimentally and theoretically. A good agreement between experimental and calculated results is shown if neglecting the filament plasma. It is shown that the Kerr nonlinearity plays a fundamental role in the generation, existence, and cessation of a filament at a small numerical aperture (NA ≤ 2.15 × 10–3). The Kerr effect first leads to the beam self-focusing and generation of a filament, and at the final stage, to radiation defocusing and a sharp decrease in its axial intensity due to the beam wavefront distortions. In the case of aberration focusing, a spatial quasi-soliton is formed after a visible filament due to the balance between Kerr self-focusing and diffraction spreading. The quasi-soliton is a source of the directional white supercontinuum.

Atmospheric and Oceanic Optics. 2017;30(4):331-336
pages 331-336 views

Remote Sensing of Atmosphere, Hydrosphere, and Underlying Surface

Remote detector of hazardous substances based on a tunable 13С16О2 laser

Ageev B.G., Klimkin A.V., Kuryak A.N., Osipov K.O., Ponomarev Y.N.

Abstract

A description of the developed prototype of a remote detector of hazardous substance vapors based on a tunable 13С16О2 laser is given. Results of test measurements of laser radiation transmission of organic liquid vapors (acetone, ammonia, ethanol, gasoline) are presented. The remote detection of acetone and ammonia vapors at distances up to 100 m is experimentally implemented.

Atmospheric and Oceanic Optics. 2017;30(4):337-341
pages 337-341 views

Atmospheric Radiation, Optical Weather, and Climate

Impact of ozone depletion on degradation processes of coniferous forests in southern regions of Siberia

Zuev V.V., Zueva N.E., Korotkova E.M., Pavlinsky A.V.

Abstract

The main factors leading to the increase in the intensity of coniferous forests focal drying in southern Siberia since the 1990s are analyzed. It is shown that a significant factor that weakens the resistance of coniferous trees could be long-term ozone depletion due to the permanent presence in the atmosphere of volcanic aerosols caused by frequent Plinian eruptions in the volcano tropical belt with VEI ≥ 4, which exposed southern Siberia to continuous exposure of high doses of short-wave UV-B radiation from 1992 to 2012.

Atmospheric and Oceanic Optics. 2017;30(4):342-348
pages 342-348 views

Optical Models and Databases

Spatiotemporal variations in aerosol characteristics along the route of the Indian-Atlantic expedition onboard the research vessel Akademik Nikolaj Strakhov

Sakerin S.M., Golobokova L.P., Kabanov D.M., Pol’kin V.V., Turchinovich Y.S., Khodzher T.V., Khuriganova O.I.

Abstract

We discuss the results of studying the physical-chemical composition of the atmospheric aerosol during expedition onboard the RV Akademik Nikolaj Strakhov carried out during winter of 2015–2016 on the route from Colombo to Kaliningrad (via Suez Canal). As compared to the Mediterranean Sea and Atlantic (near Europe), the atmosphere of the Arabian and Red Seas was characterized by higher values of most aerosol characteristics: 3–5 times larger aerosol optical depth (AOD), 4 times larger aerosol number concentration, 1.5 times larger concentrations of continent- and sea-derived ions, as well as more abundant gas admixtures (SO2, HCl, HNO3, NH3). At the same time, two seas of the Indian basin substantially differ in aerosol composition, primarily due to outflows of aerosols of different types from the continents. The largest concentrations of black carbon (2.14 μg m–3, on average), sea-derived ions (Na+, Cl, Mg2+), and NH3 are observed over the Arabian Sea; larger values of the fine component of the AOD and concentrations of “continental” ions (SO42-, Ca2+, NO3-, NH4+) and gas admixtures SO2, HCl, HNO3 are found over the Red Sea. With respect to ion composition of aerosol, most stable concentrations are noted for Ca2+ ions (less than 15% difference among the seas), and maximal spatial variations are found for NH4+ ions (the difference of up to a factor of 40).

Atmospheric and Oceanic Optics. 2017;30(4):349-359
pages 349-359 views

Long-range transport of plumes of atmospheric emissions from regional coal power plants to the South Baikal water basin

Obolkin V.A., Potemkin V.L., Makukhin V.L., Khodzher T.V., Chipanina E.V.

Abstract

We compare cases of actually observed regional transport of atmospheric pollutants to Lake Baikal against calculations according to a mathematical model. The observational data suggest that the most severe atmospheric pollution over the Lake is associated with atmospheric transport of sulfur and nitrogen dioxides from large coal-fired power plants both from the direction of Irkutsk and Angarsk, and from the direction of Buryatia (Ulan-Ude and Gusinoozersk). Transport of sulfur and nitrogen oxides to the Baikal atmosphere is especially strong at nighttime, under inversion-type meteorological conditions, in the form of weakly dispersed plumes from tall stacks of power plants. Data of automatic measurements of sulfur and nitrogen oxides demonstrate that actual mechanisms of anthropogenic pollutant transport to Lake Baikal are more complex and multiform as compared to model results. Model estimates of SO2 concentrations over the Lake are close to monthly average measurements; however, they fail to explain certain specific cases of increased pollutant concentrations in the Baikal atmosphere.

Atmospheric and Oceanic Optics. 2017;30(4):360-365
pages 360-365 views

Optical Instrumentation

Bistatic optoelectronic communication systems: Field experiments in artificial and natural water reservoirs

Belov V.V., Abramochkin V.N., Gridnev Y.V., Kudryavtsev A.N., Tarasenkov M.V., Fedosov A.V.

Abstract

Results of field experiments performed with bistatic optoelectronic communication systems in artificial and natural water reservoirs in 2015 are discussed. The experiments were aimed at estimation of the communication quality from the communication error probabilities and their standard deviations. Results of the experiments assume possibilities of creating optoelectronic communication systems capable of effectively operating in water and complex media (water–atmosphere and atmosphere–water, including ice interface) with communication line lengths from several tens to several hundreds of meters.

Atmospheric and Oceanic Optics. 2017;30(4):366-371
pages 366-371 views

Diurnal behavior of the flux and partial pressure of carbon dioxide in the surface water in solar time coordinates (the period of open water in the South Baikal littoral in 2004–2015)

Pestunov D.A., Shamrin A.M., Domysheva V.M., Sakirko M.V., Panchenko M.V.

Abstract

A long-term series of regular measurements of the carbon dioxide concentration in the surface water and СО2 fluxes in the Baikal littoral zone demonstrated a diurnal rhythm related to processes of photosynthesis activity of plankton during the entire period of open water (from May to December). To isolate the role of only the photoperiodicity process on the background of many various factors having an effect on the change in the concentration of carbon dioxide in the surface water and СО2 fluxes in the atmosphere–water system, the scheme of the diurnal behavior of СО2 during the open water period in 2007–2015 in the littoral zone of South Baikal is considered in coordinates of sunshine duration which was calculated proceeding from the theoretically possible sunshine duration (from sunrise to sunset in the case of clear sky and open horizon). The proposed scheme of parameterization and reconstruction of these characteristics for any time instant can find application in estimating calculations in carbon cycle models and be useful in planning the optimum regime for studying biological and chemical processes in Lake Baikal.

Atmospheric and Oceanic Optics. 2017;30(4):372-381
pages 372-381 views

Empirical assessment of errors in total ozone measurements with different instruments and methods

Virolainen Y.A., Timofeyev Y.M., Poberovskii A.V., Polyakov A.V., Shalamyanskii A.M.

Abstract

Knowledge of measurement errors is one of the most important issues for assessing the quality of experimental data. In this paper, we compared various methods and instruments for measuring the total ozone content (TOC) near St. Petersburg in the period from 2009 to 2015. We considered the TOC datasets of ground-based measurements at Voyeykovo (Dobson spectrophotometer and M-124 ozonometer) and Peterhof (Bruker 125HR spectrometer), as well as OMI and IASI satellite measurements. To assess the errors intrinsic to each of these instruments three ensembles of the TOC measurements were formed containing different numbers of comparisons and based on different selection criteria. At the first stage, we determined the means and standard deviations between the ensembles of the TOC measurements. Then, assuming a horizontally homogeneous and stationary ozone field, the random and systematic errors of individual methods were evaluated. The average random errors of the TOC measurements for all tree ensembles were 2.9 ± 0.5%, 2.8 ± 0.7%, 1.2 ± 0.2%, and 1.4 ± 0.1% for IASI, M-124, OMI, and Bruker 125HR, respectively. The systematic error of the standard Dobson measurements is–1.7% and–2.1% for OMI and IASI, respectively, and amounts to + 0.5% and + 2.1% for M-124 and Bruker 125HR, respectively. The OMI and Bruker 125HR TOC measurement errors are most resistant to atmospheric conditions, whereas errors in IASI and M-124 TOC measurements depend to a large extent on the state of the atmosphere.

Atmospheric and Oceanic Optics. 2017;30(4):382-388
pages 382-388 views

Adaptive and Integral Optics

Adaptation problems in the space telescope of the millimetron observatory

Sychev V.V., Klem A.I.

Abstract

The Millimetron space observatory with a 10-meter optical telescope is now being created in Russia; it is unparalleled in terms of the scale of scientific and technical problems to be solved in the study of objects in the Universe. The amount of information that can be received with this observatory largely depends on the chosen concept and manufacturability of technology that provide for the high quality of imaging by the telescope. Possible technical solutions and concepts that can form the basis for the creation of systems of adaptive correction of distortions of the incident radiation wavefront are considered based on the analysis of distorting factors. Versions of adaptive optics systems for the space telescope are considered and analyzed. The adaptation at the entrance pupil of the telescope is selected and substantiated, implemented with the circuit of parallel information reading by petals of the telescope integrated primary mirror. The circuit is suggested for real-time dynamic adjustment of the telescope adaptive control system by image analyzer signals. It is shown that visible radiation received from a field region shifted from the telescope optical axis with a random misalignment angle can be used as reference.

Atmospheric and Oceanic Optics. 2017;30(4):389-398
pages 389-398 views

A variational method for wavefront reconstruction from Shack–Hartman sensor measurements

Razgulin A.V., Kuzhamaliyev Y.Z., Goncharov A.S., Larichev A.V.

Abstract

A new technique is suggested for wavefront reconstruction from gradient measurements on the basis of solution of the variational problem. The spatial frequency transfer function is derived for its reconstructor. The reconstruction accuracy is studied at different spatial spectra of wavefront distortions in numerical simulation. The reconstructor sensitivity is analyzed in the case of data loss in some nodes of the measuring grid.

Atmospheric and Oceanic Optics. 2017;30(4):399-403
pages 399-403 views