Synthesis and catalytic activity to Li/SOCl2 battery of asymmetric and symmetric binuclear metal phthalocyanines


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详细

In our present work, the asymmetric and symmetric binuclear metal phthalocyanines (M2(PcTN)2 and M2(PcTN)2S), battery catalysts, were synthesized through microwave reaction and characterized by EA, IR and UV-vis spectroscopy. Their catalytic activity in the Li/SOCl2 battery was evaluated by adding right amount catalysts into the electrolyte. The results indicated that the capacity of the catalyzed battery increased by 6.74–67.26% and 13.41–84.36%, and the energy increased by 9.29–65.72% and 14.77–88.15% respectively, compared with the battery without phthalocyanines.

作者简介

Q. Jiang

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science

Email: jszhao@nwu.edu.cn
中国, Xi’an, Shaanxi, 710069

S. Li

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science

Email: jszhao@nwu.edu.cn
中国, Xi’an, Shaanxi, 710069

F. Yang

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science

Email: jszhao@nwu.edu.cn
中国, Xi’an, Shaanxi, 710069

N. Zhao

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science

Email: jszhao@nwu.edu.cn
中国, Xi’an, Shaanxi, 710069

F. Zhang

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science

Email: jszhao@nwu.edu.cn
中国, Xi’an, Shaanxi, 710069

J. Zhao

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science

编辑信件的主要联系方式.
Email: jszhao@nwu.edu.cn
中国, Xi’an, Shaanxi, 710069

S. Zhang

School of Material Science and Engineering

Email: jszhao@nwu.edu.cn
中国, XueYuan Road No.37, HaiDian District, Beijing, 100191

J. Wang

Composites Research Institute

Email: jszhao@nwu.edu.cn
中国, Weinan, 714000

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