Email this article Synthesis and catalytic activity to Li/SOCl2 battery of asymmetric and symmetric binuclear metal phthalocyanines
- Authors: Jiang Q.Q.1, Li S.W.1, Yang F.1, Zhao N.1, Zhang F.X.1, Zhao J.S.1, Zhang S.C.2, Wang J.L.3
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Affiliations:
- Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
- School of Material Science and Engineering
- Composites Research Institute
- Issue: Vol 52, No 2 (2016)
- Pages: 136-142
- Section: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/187726
- DOI: https://doi.org/10.1134/S102319351602004X
- ID: 187726
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Abstract
In our present work, the asymmetric and symmetric binuclear metal phthalocyanines (M2(PcTN)2 and M2(PcTN)2S), battery catalysts, were synthesized through microwave reaction and characterized by EA, IR and UV-vis spectroscopy. Their catalytic activity in the Li/SOCl2 battery was evaluated by adding right amount catalysts into the electrolyte. The results indicated that the capacity of the catalyzed battery increased by 6.74–67.26% and 13.41–84.36%, and the energy increased by 9.29–65.72% and 14.77–88.15% respectively, compared with the battery without phthalocyanines.
About the authors
Q. Q. Jiang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Email: jszhao@nwu.edu.cn
China, Xi’an, Shaanxi, 710069
S. W. Li
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Email: jszhao@nwu.edu.cn
China, Xi’an, Shaanxi, 710069
F. Yang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Email: jszhao@nwu.edu.cn
China, Xi’an, Shaanxi, 710069
N. Zhao
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Email: jszhao@nwu.edu.cn
China, Xi’an, Shaanxi, 710069
F. X. Zhang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Email: jszhao@nwu.edu.cn
China, Xi’an, Shaanxi, 710069
J. S. Zhao
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Author for correspondence.
Email: jszhao@nwu.edu.cn
China, Xi’an, Shaanxi, 710069
S. C. Zhang
School of Material Science and Engineering
Email: jszhao@nwu.edu.cn
China, XueYuan Road No.37, HaiDian District, Beijing, 100191
J. L. Wang
Composites Research Institute
Email: jszhao@nwu.edu.cn
China, Weinan, 714000
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