Synthesis and catalytic activity to Li/SOCl2 battery of asymmetric and symmetric binuclear metal phthalocyanines
- Авторлар: Jiang Q.1, Li S.1, Yang F.1, Zhao N.1, Zhang F.1, Zhao J.1, Zhang S.2, Wang J.3
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Мекемелер:
- Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
- School of Material Science and Engineering
- Composites Research Institute
- Шығарылым: Том 52, № 2 (2016)
- Беттер: 136-142
- Бөлім: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/187726
- DOI: https://doi.org/10.1134/S102319351602004X
- ID: 187726
Дәйексөз келтіру
Аннотация
In our present work, the asymmetric and symmetric binuclear metal phthalocyanines (M2(PcTN)2 and M2(PcTN)2S), battery catalysts, were synthesized through microwave reaction and characterized by EA, IR and UV-vis spectroscopy. Their catalytic activity in the Li/SOCl2 battery was evaluated by adding right amount catalysts into the electrolyte. The results indicated that the capacity of the catalyzed battery increased by 6.74–67.26% and 13.41–84.36%, and the energy increased by 9.29–65.72% and 14.77–88.15% respectively, compared with the battery without phthalocyanines.
Негізгі сөздер
Авторлар туралы
Q. Jiang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Email: jszhao@nwu.edu.cn
ҚХР, Xi’an, Shaanxi, 710069
S. Li
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Email: jszhao@nwu.edu.cn
ҚХР, Xi’an, Shaanxi, 710069
F. Yang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Email: jszhao@nwu.edu.cn
ҚХР, Xi’an, Shaanxi, 710069
N. Zhao
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Email: jszhao@nwu.edu.cn
ҚХР, Xi’an, Shaanxi, 710069
F. Zhang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Email: jszhao@nwu.edu.cn
ҚХР, Xi’an, Shaanxi, 710069
J. Zhao
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science
Хат алмасуға жауапты Автор.
Email: jszhao@nwu.edu.cn
ҚХР, Xi’an, Shaanxi, 710069
S. Zhang
School of Material Science and Engineering
Email: jszhao@nwu.edu.cn
ҚХР, XueYuan Road No.37, HaiDian District, Beijing, 100191
J. Wang
Composites Research Institute
Email: jszhao@nwu.edu.cn
ҚХР, Weinan, 714000