Effect of ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide on the properties of poly(glycidyl methacrylate) based solid polymer electrolytes
- Authors: Imperiyka M.1, Hanifah S.A.2, Ahmad A.2,3, Hassan N.H.2, Rahman M.Y.4, Nabilah M.R.2, Alwi M.A.2, Su’ait M.S.3
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Affiliations:
- Faculty of Arts and Sciences, Kufra Campus
- School of Chemical Sciences and Food Technology, Faculty of Science and Technology
- Solar Energy Research Institute (SERI)
- Institute of Microengineering and Nanoelectronics (IMEN)
- Issue: Vol 52, No 4 (2016)
- Pages: 362-373
- Section: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/187820
- DOI: https://doi.org/10.1134/S1023193516040091
- ID: 187820
Cite item
Abstract
A free standing polymer electrolytes films, containing poly(glycidyl methacrylate) (PGMA) as the polymer host, lithium perchlorate (LiClO4), and ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl) imide [Bmim][TFSI] as a plasticizer was successfully prepared via the solution casting method. The XRD analysis revealed the amorphous nature of the electrolyte. ATR-FTIR and thermal studies confirmed the interaction and complexation between the polymer host and the ionic liquid. The maximum ionic conductivity of the solid polymer electrolyte was found at 2.56 × 10–5 S cm–1 by the addition of 60 wt % [Bmim][TFSI] at room temperature and increased up to 3.19 × 10–4 S cm–1 at 373 K, as well as exhibited a transition of temperature dependence of conductivity: Arrhenius-like behavior at low and high temperatures.
About the authors
M. Imperiyka
Faculty of Arts and Sciences, Kufra Campus
Email: mohd.yusri@ukm.edu.my
Libya, Al Kufrah
S. A. Hanifah
School of Chemical Sciences and Food Technology, Faculty of Science and Technology
Email: mohd.yusri@ukm.edu.my
Malaysia, Bangi, Selangor, 43600
A. Ahmad
School of Chemical Sciences and Food Technology, Faculty of Science and Technology; Solar Energy Research Institute (SERI)
Email: mohd.yusri@ukm.edu.my
Malaysia, Bangi, Selangor, 43600; Bangi, Selangor, 43600
N. H. Hassan
School of Chemical Sciences and Food Technology, Faculty of Science and Technology
Author for correspondence.
Email: syareeda@ukm.edu.my
Malaysia, Bangi, Selangor, 43600
M. Y. A. Rahman
Institute of Microengineering and Nanoelectronics (IMEN)
Author for correspondence.
Email: mohd.yusri@ukm.edu.my
Malaysia, Bangi, Selangor, 43600
M. R. N. Nabilah
School of Chemical Sciences and Food Technology, Faculty of Science and Technology
Email: mohd.yusri@ukm.edu.my
Malaysia, Bangi, Selangor, 43600
M. A. Alwi
School of Chemical Sciences and Food Technology, Faculty of Science and Technology
Email: mohd.yusri@ukm.edu.my
Malaysia, Bangi, Selangor, 43600
M. S. Su’ait
Solar Energy Research Institute (SERI)
Email: mohd.yusri@ukm.edu.my
Malaysia, Bangi, Selangor, 43600