Kinetic Analysis of Isobutylene Synthesis from Ethanol in the Presence of ZnO/ZrO2


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Kinetic analysis of isobutylene synthesis from ethanol in the presence of a ZnO/ZrO2 catalyst synthesized by incipient wetness impregnation of zirconium hydroxide with zinc nitrate has been conducted. Analysis data have been used to determine primary, secondary, stable, and unstable products. The selectivity for the reaction products and the order of their formation have been determined. A general scheme of the reaction routes for ethanol conversion to isobutylene has been proposed.

作者简介

O. Ponomareva

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University

编辑信件的主要联系方式.
Email: oaponomareva@phys.chem.msu.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991

P. Shaposhnik

Faculty of Chemistry, Moscow State University

Email: oaponomareva@phys.chem.msu.ru
俄罗斯联邦, Moscow, 119991

S. Konnov

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: oaponomareva@phys.chem.msu.ru
俄罗斯联邦, Moscow, 119991

B. Kolozhvari

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University

Email: oaponomareva@phys.chem.msu.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991

I. Ivanova

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University

Email: oaponomareva@phys.chem.msu.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991

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