Email this article Kinetic Analysis of Isobutylene Synthesis from Ethanol in the Presence of ZnO/ZrO2
- Authors: Ponomareva O.A.1,2, Shaposhnik P.A.2, Konnov S.V.1, Kolozhvari B.A.1,2, Ivanova I.I.1,2
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Affiliations:
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Faculty of Chemistry, Moscow State University
- Issue: Vol 59, No 8 (2019)
- Pages: 935-940
- Section: Article
- URL: https://journals.rcsi.science/0965-5441/article/view/180980
- DOI: https://doi.org/10.1134/S0965544119080164
- ID: 180980
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Abstract
Kinetic analysis of isobutylene synthesis from ethanol in the presence of a ZnO/ZrO2 catalyst synthesized by incipient wetness impregnation of zirconium hydroxide with zinc nitrate has been conducted. Analysis data have been used to determine primary, secondary, stable, and unstable products. The selectivity for the reaction products and the order of their formation have been determined. A general scheme of the reaction routes for ethanol conversion to isobutylene has been proposed.
About the authors
O. A. Ponomareva
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Author for correspondence.
Email: oaponomareva@phys.chem.msu.ru
Russian Federation, Moscow, 119991; Moscow, 119991
P. A. Shaposhnik
Faculty of Chemistry, Moscow State University
Email: oaponomareva@phys.chem.msu.ru
Russian Federation, Moscow, 119991
S. V. Konnov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: oaponomareva@phys.chem.msu.ru
Russian Federation, Moscow, 119991
B. A. Kolozhvari
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Email: oaponomareva@phys.chem.msu.ru
Russian Federation, Moscow, 119991; Moscow, 119991
I. I. Ivanova
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Email: oaponomareva@phys.chem.msu.ru
Russian Federation, Moscow, 119991; Moscow, 119991
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