Enviar artigo por via de e-mail Kinetic Analysis of Isobutylene Synthesis from Ethanol in the Presence of ZnO/ZrO2
- Autores: Ponomareva O.A.1,2, Shaposhnik P.A.2, Konnov S.V.1, Kolozhvari B.A.1,2, Ivanova I.I.1,2
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Afiliações:
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Faculty of Chemistry, Moscow State University
- Edição: Volume 59, Nº 8 (2019)
- Páginas: 935-940
- Seção: Article
- URL: https://journals.rcsi.science/0965-5441/article/view/180980
- DOI: https://doi.org/10.1134/S0965544119080164
- ID: 180980
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Resumo
Kinetic analysis of isobutylene synthesis from ethanol in the presence of a ZnO/ZrO2 catalyst synthesized by incipient wetness impregnation of zirconium hydroxide with zinc nitrate has been conducted. Analysis data have been used to determine primary, secondary, stable, and unstable products. The selectivity for the reaction products and the order of their formation have been determined. A general scheme of the reaction routes for ethanol conversion to isobutylene has been proposed.
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Sobre autores
O. Ponomareva
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Autor responsável pela correspondência
Email: oaponomareva@phys.chem.msu.ru
Rússia, Moscow, 119991; Moscow, 119991
P. Shaposhnik
Faculty of Chemistry, Moscow State University
Email: oaponomareva@phys.chem.msu.ru
Rússia, Moscow, 119991
S. Konnov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: oaponomareva@phys.chem.msu.ru
Rússia, Moscow, 119991
B. Kolozhvari
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Email: oaponomareva@phys.chem.msu.ru
Rússia, Moscow, 119991; Moscow, 119991
I. Ivanova
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Email: oaponomareva@phys.chem.msu.ru
Rússia, Moscow, 119991; Moscow, 119991
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