Enviar artigo por via de e-mail Identification of Free Radicals Generated by Different Curing Modes in a Dental Resin Cement
- Autores: Vicentin B.1, Netto A.2, Blümich B.2, Di Mauro E.1
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Afiliações:
- Department of Physics, State University of Londrina
- Institute of Technical and Macromolecular Chemistry, RWTH Aachen University
- Edição: Volume 47, Nº 9 (2016)
- Páginas: 1003-1014
- Seção: Article
- URL: https://journals.rcsi.science/0937-9347/article/view/247515
- DOI: https://doi.org/10.1007/s00723-016-0803-7
- ID: 247515
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Resumo
The polymerization process of the dual cure resin cement AllCem (FGM, Joinvile, Brazil) was investigated theoretically and experimentally. The free radicals responsible for polymerization continuity were characterized by multi-frequency EPR spectroscopy (X-, Q- and W-band) and spectra simulation. It was observed by multifrequency electron paramagnetic resonance spectroscopy and spectra simulation that the paramagnetic species occur simultaneously and independently for both self-cure and photo-cure modes. The paramagnetic species generating the EPR signal are the same for both photo-cure and self-cure polymerization mechanisms.
Sobre autores
Bruno Vicentin
Department of Physics, State University of Londrina
Autor responsável pela correspondência
Email: bruno.vicentin@uel.br
Brasil, Rodovia Celso Garcia Cid PR-445 km 380, Londrina, 86057-970
Antonio Netto
Institute of Technical and Macromolecular Chemistry, RWTH Aachen University
Email: bruno.vicentin@uel.br
Alemanha, Aachen
Bernhard Blümich
Institute of Technical and Macromolecular Chemistry, RWTH Aachen University
Email: bruno.vicentin@uel.br
Alemanha, Aachen
Eduardo Di Mauro
Department of Physics, State University of Londrina
Email: bruno.vicentin@uel.br
Brasil, Rodovia Celso Garcia Cid PR-445 km 380, Londrina, 86057-970
