Enviar artigo por via de e-mail Reaction of 2-hydroxy-5-methylacetophenone chalcones with guanidine in the presence of hydrogen peroxide
- Autores: Mamedov I.1, Khrustalev V.2,3
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Afiliações:
- Baku State University
- Peoples’ Friendship University of Russia (RUDN University)
- N.D. Zelinsky Institute of Organic Chemistry RAS
- Edição: Volume 59, Nº 9 (2023)
- Páginas: 1238-1242
- Seção: Articles
- URL: https://journals.rcsi.science/0514-7492/article/view/141693
- DOI: https://doi.org/10.31857/S051474922309015X
- EDN: https://elibrary.ru/XVFPLQ
- ID: 141693
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Resumo
In the presented work, the reaction of two 2-hydroxy-5-methylacetophenone chalcones and guanidine was investigated in the presence of hydrogen peroxide. Depending on the structure of the chalcones a 4.6-diaryl-2-aminopyrimidine or flavanol was obtained. The structures of the obtained products were elucidated by NMR spectroscopy and X-ray crystallography. Reaction route formation of compounds was proposed.
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Sobre autores
I. Mamedov
Baku State University
Email: bsu.nmrlab@gmail.com
V. Khrustalev
Peoples’ Friendship University of Russia (RUDN University);N.D. Zelinsky Institute of Organic Chemistry RAS
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