A New Approach to (2,2'-bi)Pyridines with (Triptycene-2-yl)Amine Moiety

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Abstract

An effective synthetic approach to (2,2'-bi)pyridines having a fragment of ((9r,10r)-9,10-dihydro-9,10-[1,2]benzenoanthracene-2-yl)amine ((tryptycene-2-yl)amine) in the alpha position via their 1,2,4-triazine precursors has been proposed; the synthesis was made as a result of the nucleophilic ipso substitution of the cyano group at the C5 position of 3-(2-pyridyl)-1,2,4-triazines and the subsequent Bodger reaction with 2,5-norbornadiene.

About the authors

S. S Potapova

Ural Federal University named after the first President of Russia B.N. Yeltsin; Postovsky Institute of Organic Synthesis, UB, RAS

Email: sveta.rybakova.2000@mail.ru
Yekaterinburg, Russia; Yekaterinburg, Russia

M. I Valieva

Ural Federal University named after the first President of Russia B.N. Yeltsin; Postovsky Institute of Organic Synthesis, UB, RAS

Yekaterinburg, Russia; Yekaterinburg, Russia

E. A Kudryashova

Ural Federal University named after the first President of Russia B.N. Yeltsin

Yekaterinburg, Russia

D. S Kopchuk

Ural Federal University named after the first President of Russia B.N. Yeltsin; Postovsky Institute of Organic Synthesis, UB, RAS

Yekaterinburg, Russia; Yekaterinburg, Russia

Т. А. Pospelovaa

Ural Federal University named after the first President of Russia B.N. Yeltsin

Yekaterinburg, Russia

G. V Zyryanov

Ural Federal University named after the first President of Russia B.N. Yeltsin; Postovsky Institute of Organic Synthesis, UB, RAS

Yekaterinburg, Russia; Yekaterinburg, Russia

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