ELECTROCHEMICAL BEHAVIOR OF DIMETHYLSULPHONE ON A PLATINUM ELECTRODE
- 作者: Akhmedov M.1,2, Khidirov S.3, Suleymanov S.1
-
隶属关系:
- Analytical Center for Collective Use of the Far Eastern Federal Research Center of the Russian Academy of Sciences
- Limited Liability Company "Daglithium"
- Dagestan State University
- 期: 卷 59, 编号 11 (2023)
- 页面: 674-685
- 栏目: Articles
- URL: https://journals.rcsi.science/0424-8570/article/view/232650
- DOI: https://doi.org/10.31857/S0424857023110038
- EDN: https://elibrary.ru/NWHREX
- ID: 232650
如何引用文章
详细
In this work, we studied the effect of dimethylsulfone concentrations on the rate of anodic oxygen evolution and cathodic hydrogen evolution on a platinum electrode in acidic and alkaline media. By the method of calculating the DFT electron density functional at the level of the B97-3c theory using the Orca 4.2.0 program, the dimethyl sulfone bond breaking energy on the surface of platinum will be preferable through C-S bonds, according to the ion-radical mechanism. It has been confirmed by NMR and Raman spectroscopy that the end products of the anodic oxidation of dimethylsulfone in an acidic medium are methanesulfonic acid and dimethyldisulfone, in an alkaline medium - only dimethyldisulfone; the end products of cathodic reduction of DMSO2 are dimethylpolysulfides. Based on the obtained experimental results, a scheme of the electrocatalytic behavior of dimethylsulfone on a platinum electrode is proposed.
作者简介
M. Akhmedov
Analytical Center for Collective Use of the Far Eastern Federal Research Center of the Russian Academy of Sciences; Limited Liability Company "Daglithium"
Email: muhamadahmedov@mail.ru
Makhachkala, Russia; Makhachkala, Russia
Sh. Khidirov
Dagestan State University
Email: khidirovdgu@mail.ru
Makhachkala, Russia
S. Suleymanov
Analytical Center for Collective Use of the Far Eastern Federal Research Center of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: khidirovdgu@mail.ru
Россия, Махачкала
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