Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO13

R. D. Andreev; Андреев Р. Д.; I. A. Anokhina; Анохина И. А.; D. V. Korona; Корона Д. В.; A. R. Gilev; Гилев А. Р.; I, E. Animitsa; Анимица И. Е.

doi:10.31857/S0424857023030039

Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO13

作者: Andreev R.¹^,2, Anokhina I.¹^,2, Korona D.¹^,2, Gilev A.¹, Animitsa I.¹
隶属关系:
1. Ural Federal University named after the First President of Russia B.N. Yeltsin
2. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
期: 卷 59, 编号 3 (2023)
页面: 143-157
栏目: Articles
URL: https://journals.rcsi.science/0424-8570/article/view/139245
DOI: https://doi.org/10.31857/S0424857023030039
EDN: https://elibrary.ru/HWGJUV
ID: 139245

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详细

A complex oxide Ba5In1.9Y0.1Al2ZrO13 with hexagonal perovskite structure (a = 5.971(4) Å, с = 24.012(1) Å) is prepared for the first time. The phase is found to dissociative-absorb water from gas phase, the degree of hydration being as high as 0.39 mol Н2О. It was found by using IR-spectroscopy that protons are present therein as energetically nonequivalent ОН–-groups involved in hydrogen bonds of diverse strength. Isovalent yttrium-doping of the Ba5In2Al2ZrO13 phase is shown not to lead to any valuable change in the oxygen-ion-conductivity as compared with the Ba5In2.1Al2Zr0.9O12.95 acceptor doping that allows increasing the oxygen-ion-conductivity by a factor of 1.3. Both types of doping lead to increase in the proton conductivity and, as a corollary to this, an increase in the proton concentration. For these phases the degree of hydration depends on the cell parameters, hence, is determined by space availability for ОН–-groups in the barium coordination. Proton transport dominates in the Ba5In2Al2ZrO13, Ba5In2.1Al2Zr0.9O12.95, and Ba5In1.9Y0.1Al2ZrO13 phases below 600оС in humid atmosphere (pH2О = 1.92 × 10–2 atm).

关键词

hexagonal perovskite, hydration, proton conductivity

参考

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