Electron microscopy and electron energy loss spectroscopy of titanium nitride thin films in TiNx/La: HfO2 (Hf0.5Zr0.5O)/TiNx/SiO2

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Abstract

The structure and properties of TiNx electrodes obtained by plasma-enhanced atomic layer deposition in the 20 nm TiNx/10 nm La: HfO2(Hf0.5Zr0.5O)/20 nm TiNx/1 μm SiO2 system have been studied by electron microscopy and electron energy loss spectroscopy. It is shown that the electrode material has a TiNxOy composition, the band gap width varies within 1.7–2.5 eV, the resistivity is 208 μOm cm and the value of the temperature coefficient of resistance (20–100°C) is equal to –31.4 ⋅ 10–6 1/K.

About the authors

E. I. Suvorova

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics”
of the Russian Academy of Sciences

Author for correspondence.
Email: suvorova@crys.ras.ru
Russia, 119333, Moscow

O. V. Uvarov

Prokhorov General Physics Institute of Russian Academy of Sciences

Email: suvorova@crys.ras.ru
Russia, 119991, Moscow

A. A. Klimenko

Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences

Email: suvorova@crys.ras.ru
Russia, 119991, Moscow

K. V. Chizh

Prokhorov General Physics Institute of Russian Academy of Sciences; Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences

Email: suvorova@crys.ras.ru
Russia, 119991, Moscow; Russia, 119991, Moscow

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Copyright (c) 2023 Е.И. Суворова, О.В. Уваров, А.А. Клименко, К.В. Чиж

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