Phase formation and structure in the solid solutions of the (1 –  х )BiFeO 3 – x /2PbFe 1/2 NB 1/2 O 3 – x /2PbFe 2/3 W 1/3 O 3  system

E. V. Glazunova; Глазунова Е. В.; L. A. Shilkina; Шилкина Л. А.; A. V. Nagaenko; Нагаенко А. В.; I. A. Verbenko; Вербенко И. А.; L. A. Reznichenko; Резниченко Л. А.

doi:10.31857/S0367676523702216

Phase formation and structure in the solid solutions of the (1 – х)BiFeO₃–x/2PbFe_1/2NB_1/2O₃–x/2PbFe_2/3W_1/3O₃ system

Authors: Glazunova E.V.¹, Shilkina L.A.¹, Nagaenko A.V.², Verbenko I.A.¹, Reznichenko L.A.¹
Affiliations:
1. Institute of Physics, Southern Federal University
2. Institute of High Technologies and Piezotechnics, Southern Federal University
Issue: Vol 87, No 9 (2023)
Pages: 1255-1261
Section: Articles
URL: https://journals.rcsi.science/0367-6765/article/view/135480
DOI: https://doi.org/10.31857/S0367676523702216
EDN: https://elibrary.ru/KETQSP
ID: 135480

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

The solid solutions of the (1 – х)BiFeO₃–x/2PbFe_1/2Nb_1/2O₃–x/2PbFe_2/3W_1/3O₃ system in the concentration range 0.05 ≤ х ≤ 0.50 were produced by solid state method and sintering using conventional ceramic technology. In the range 0.25 < x < 0.35, a morphotropic phase transition from the rhombohedral phase to the cubic phase was found. The difference in symmetry when “scaling” the material is shown. The influence of PbFe_1/2Nb_1/2O₃ and PbFe_2/3W_1/3O₃ on the grain structure formation was established.

References

Фесенко Е.Г. Семейство перовскита и сегнетоэлектричество. М.: Атомиздат, 1972. 248 с.
Phapale S., Mishra R., Das D. // J. Nucl. Mater. 2008. V. 373. P. 137.
Carvalho T.T., Tavares P.B. // Mater. Lett. 2008. V. 62. P. 3984.
Matteppenevar Sh., Rayaprol S., Angadi B., Sahoo B. // J. Alloys Compounds. 2016. V. 677. No. 8. P. 27.
Matteppanavar S., Shivaraja I., Rayaprol S. et al. // J. Supercond. Nov. Magn. 2017. V. 30. No. 5. Art. No. 1317.
Nagaraja T., Dadami S. T., Matteppanvar S. et al. // AIP Conf. Proc. 2018. V. 1942. Art. No. 140041.
Nagaraja T., Dadami S.T., Basavaraj Angadi // AIP Conf. Proc. 2018. V. 1953. Art. No. 070013.
Li H., Zhuang J., Bokov A.A. et al. // J. Eur. Ceram. 2021. V. 41. P. 310.
Shivaraja I., Matteppanavar S., Deshpande S.K. et al. // J. Alloys Compounds. 2019. V. 800. P. 334.
Zhu W.M., Ye Z.-G. // Ceram. Int. 2004. V. 30. P. 1435.
Садыков Х.А., Вербенко И.А., Резниченко Л.А. и др. // Констр. композ. матер. 2013. № 2. С. 50.
Powder diffraction file. Data card. Inorganic section. Set 42, card 181. Swarthmore: JCPDS, 1948.
Powder diffraction file. Data card. Inorganic section. Set 20, card 836. Swarthmore: JCPDS, 1948.
Вест А. Химия твердого тела теория и приложения. Часть 1. М.: Мир, 1988. 558 с.
Галахов Ф.Н. Диаграммы состояния систем тугоплавких оксидов. Вып. 5. Ч. 4. Л.: Наука, 1988. 348 с.
Галахов Ф.Н. Диаграммы состояния систем тугоплавких оксидов. Вып. 5. Ч. 2. Л.: Наука, 1986. 359 с.
Ma J., Ma W., Li Q. et al. // J. Mater. Sci. Mater Electron. 2014. V. 25. P. 3695.
Shi J., Chen X., Sun C. et al. // Ceram. Int. 2020. V. 46. P. 25731.