Phase formation and structure in the solid solutions of the (1 –  х )BiFeO 3 – x /2PbFe 1/2 NB 1/2 O 3 – x /2PbFe 2/3 W 1/3 O 3  system

E. V. Glazunova; Глазунова Е. В.; L. A. Shilkina; Шилкина Л. А.; A. V. Nagaenko; Нагаенко А. В.; I. A. Verbenko; Вербенко И. А.; L. A. Reznichenko; Резниченко Л. А.

doi:10.31857/S0367676523702216

Phase formation and structure in the solid solutions of the (1 – х)BiFeO₃–x/2PbFe_1/2NB_1/2O₃–x/2PbFe_2/3W_1/3O₃ system

作者: Glazunova E.¹, Shilkina L.¹, Nagaenko A.², Verbenko I.¹, Reznichenko L.¹
隶属关系:
1. Institute of Physics, Southern Federal University
2. Institute of High Technologies and Piezotechnics, Southern Federal University
期: 卷 87, 编号 9 (2023)
页面: 1255-1261
栏目: Articles
URL: https://journals.rcsi.science/0367-6765/article/view/135480
DOI: https://doi.org/10.31857/S0367676523702216
EDN: https://elibrary.ru/KETQSP
ID: 135480

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详细

The solid solutions of the (1 – х)BiFeO₃–x/2PbFe_1/2Nb_1/2O₃–x/2PbFe_2/3W_1/3O₃ system in the concentration range 0.05 ≤ х ≤ 0.50 were produced by solid state method and sintering using conventional ceramic technology. In the range 0.25 < x < 0.35, a morphotropic phase transition from the rhombohedral phase to the cubic phase was found. The difference in symmetry when “scaling” the material is shown. The influence of PbFe_1/2Nb_1/2O₃ and PbFe_2/3W_1/3O₃ on the grain structure formation was established.

参考

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