Characteristics of the Structural State of Bismuth Ions in Bismuth-Borate Glasses


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Abstract

The properties and graphical plots of the properties of bismuth-borate glasses in a wide range of compositions—20 to 80 mol.% Bi2O3 —are presented. In multi-bismuth glasses both the boron and bismuth ions are found in two coordination states: B3+, B4+ and Bi3+, Bi6+. The [BiO3] groups play the role of a conventional glass former but manifest weakly in the IR spectra.

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N. M. Bobkova

Belarusian State Technological University

Author for correspondence.
Email: bobkova@belstu.by
Belarus, Minsk

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