Effect of Calcium, Barium, and Strontium on the Thermal Properties of Borosilicate Glasses


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Abstract

The effect of additions of calcium, barium, and strontium oxides on the thermal properties of sodium fluorosilicate glasses was studied by means of differential scanning calorimetry. The data obtained from the thermal studies are compared with the results of structural studies of these glasses, and the factors determining the observed change of vitrification temperature and specific heat are established. The obtained results make it possible to adjust the parameters of synthesis and heat treatment of matrix glass-containing borosilicate materials used for immobilization of radioactive waste.

About the authors

V. E. Eremyashev

Southern Urals State University; Institute of Mineralogy, Urals Branch of the Russian Academy of Sciences

Author for correspondence.
Email: vee-zlat@mineralogy.ru
Russian Federation, Chelyabinsk; Miass, Chelyabinsk Oblast

D. A. Zherebtsov

Southern Urals State University

Email: vee-zlat@mineralogy.ru
Russian Federation, Chelyabinsk

L. M. Osipova

Institute of Mineralogy, Urals Branch of the Russian Academy of Sciences

Email: vee-zlat@mineralogy.ru
Russian Federation, Miass, Chelyabinsk Oblast

M. V. Brazhnikov

Southern Urals State University

Email: vee-zlat@mineralogy.ru
Russian Federation, Chelyabinsk

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