Electrochemical production of zirconium silicides from KCl–K₂SiF₆–ZrO₂ melt

The unique properties of zirconium silicides attract the attention of a large number of authors from various scientific fields. Expansion of application methods also poses the challenge of developing new, more environmentally friendly and affordable methods of production. The most environmentally friendly method without equipment requirements is the electrolysis of the molten salt. The work proposes a method for producing zirconium silicides by electrolysis of the KCl–K₂SiF₆–ZrO₂ melt. In order to substantiate the electrolysis parameters, the kinetics of cathodic reduction was studied and the limiting stage of the process was determined. The structure and phase composition of the cathode deposit were studied using X-ray diffraction and electron scanning microscopy. In the course of the work, conclusions were drawn about the change in the content of the ZrO₂ additives on the morphology of the sediment, and it was also suggested that it was possible to obtain zirconium silicides from more accessible raw materials, such as zircon.