A Thermodynamic Model of the Water–Rock Interaction under Hydrothermal Exposure of the Bazhenov Formation

Abstract

Thermodynamic modeling of the hydrothermal exposure of the rocks of the Bazhenov Formation resulted in revealing the equilibrium mineral associations at 50–350°C and the pressure of saturated water vapor. The calculation results show that mineral parageneses varied slightly with the increase of temperature. Thus, zeolites were characterized by the stilbite–laumontite–wairakite series; kaolinite, pyrite, dolomite, and brannerite were replaced by montmorillonite and/or albite, pyrrhotite, calcite, and uraninite, respectively. The modeling results were confirmed in experiments.