Mixed-ligand complex [Cu4(bpy)4(PO4)2(CO3)(H2O)2]: synthesis, crystal structure and biological properties
- 作者: Koshenskova K.1, Makarenko N.2, Baravikov D.1,3, Dolgushin F.1, Bekker O.4, Eremenko I.1,5, Lutsenko I.1
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隶属关系:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
- Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, Vladivostok, Russia
- Mendeleev University of Chemical Technology of Russia, Moscow, Russia
- Vavilov Institute of General Genetics, Russian Academy of Sciences, Moscow, Russia
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
- 期: 卷 49, 编号 12 (2023)
- 页面: 752-759
- 栏目: Articles
- URL: https://journals.rcsi.science/0132-344X/article/view/162367
- DOI: https://doi.org/10.31857/S0132344X23600455
- EDN: https://elibrary.ru/LQRIPR
- ID: 162367
如何引用文章
详细
The interaction in the system {Сu(OAc)2·H2O–phytic acid–2,2`-bipyridine (bpy)} in an aqueous-methanol solution led to the formation of a molecular mixed-ligand tetranuclear complex [(Cu4(bpy)4(PO4)2(CO3 )(H2O)2]13H2O (I), the structure of which was established based on the results of an X-ray diffraction experiment (CCDC 2262998). According to X-ray diffraction data, the molecule contains four nonequivalent Cu2+ cations, which coordinate two phosphate anions (PO43-, remaining as a result transformation of the phytate cycle), four neutral bpy, two water molecules and one carbonate anion fragment (CO32-). The presence of a large number of solvate water molecules in the outer coordination sphere created a hydrogen-bonded framework involved in the stabilization of the crystal packing. Study of antimycobacterial activity of I in against the non-pathogenic strain Mycolicibacterium smegmatis showed its high bioeffectiveness.
作者简介
K. Koshenskova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: irinalu05@rambler.ru
Россия, Москва
N. Makarenko
Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, Vladivostok, Russia
Email: makarenko@ich.dvo.ru
Россия, Владивосток
D. Baravikov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia; Mendeleev University of Chemical Technology of Russia, Moscow, Russia
Email: irinalu05@rambler.ru
Россия, Москва; Россия, Москва
F. Dolgushin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: fmdolgushin@gmail.com
Россия, Москва
O. Bekker
Vavilov Institute of General Genetics, Russian Academy of Sciences, Moscow, Russia
Email: irinalu05@rambler.ru
Россия, Москва
I. Eremenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
Email: irinalu05@rambler.ru
Россия, Москва; Россия, Москва
I. Lutsenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
编辑信件的主要联系方式.
Email: irinalu05@rambler.ru
Россия, Москва
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