Исследование возможности переноса насыщения в новом комплексе никеля(II) с 2,6- бис (пиразол-3-ил)пиридином

D. Yu. Aleshin; Алешин Д. Ю.; I. A.  Nikovskii; Никовский И. А.; E. A. Khakina; Хакина Е. А.; A. A.  Danshina; Даньшина А. А.; Yu. V. Nelyubina; Нелюбина Ю. В.

doi:10.31857/S0132344X22600552

Исследование возможности переноса насыщения в новом комплексе никеля(II) с 2,6-бис(пиразол-3-ил)пиридином

作者: Aleshin D.¹, Nikovskii I.¹, Khakina E.¹^,2, Danshina A.¹^,3, Nelyubina Y.¹^,4
隶属关系:
1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
2. Russia National Research University Higher School of Economics Moscow, Russia
3. Moscow Institute of Physics and Technology (National Research University), Dolgoprudnyi, Moscow oblast, Russia
4. Bauman State Technical University, Moscow, Russia
期: 卷 49, 编号 12 (2023)
页面: 737-743
栏目: Articles
URL: https://journals.rcsi.science/0132-344X/article/view/162365
DOI: https://doi.org/10.31857/S0132344X22600552
EDN: https://elibrary.ru/FIJWIJ
ID: 162365

如何引用文章

全文:

开放存取

##reader.subscriptionAccessGranted##
受限制的访问

订阅存取

详细
作者简介
参考
补充文件
统计

详细

By reacting the N,N'-disubstituted 2,6-bis(pyrazol-3-yl)pyridine ligand (L) with a divalent nickel salt, a new nickel(II) complex [Ni(L)(H2O)(THF)Cl]BPh4 was obtained (I), which was isolated in individual form and characterized by elemental analysis, mass spectrometry, NMR spectroscopy and X-ray diffraction (CCDC No. 2221412). According to NMR spectroscopy data in combination with the results of quantum chemical calculations, complex I in solution does not exhibit a saturation transfer effect.

关键词

bis(pyrazol-3-yl)pyridine, NMR spectroscopy, nickel(II) complexes, X-ray diffraction analysis, CEST effect

作者简介

D. Aleshin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

Email: unelya@ineos.ac.ru
Россия, Москва

I. Nikovskii

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

Email: unelya@ineos.ac.ru
Россия, Москва

E. Khakina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Russia National Research University Higher School of Economics Moscow, Russia

Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Москва

A. Danshina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Moscow Institute of Physics and Technology (National Research University), Dolgoprudnyi, Moscow oblast, Russia

Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Долгопрудный

Yu. Nelyubina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Bauman State Technical University, Moscow, Russia

编辑信件的主要联系方式.
Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Москва

参考

Bleackley M.R., MacGillivray R.T.A. // Biometals. 2011. V. 24. № 5. P. 785.
Wahsner J., Gale E.M., Rodriguez-Rodriguez A. et al. // Chem. Rev. 2019. V. 119. № 2. P. 957.
Jones K.M., Pollard A.C., Pagel M.D. // J. Magnetic Resonance Imaging. 2018. V. 47. № 1. P. 11.
Hancu I., Dixon W.T., Woods M. et al. // Acta Radiologica. 2010. V. 51. № 8. P. 910.
Parigi G., Ravera E., Luchinat C. // Prog. Nucl. Magn. Reson. Spectrosc. 2019. V. 114. P. 211.
Dorazio S.J., Olatunde A.O., Tsitovich P.B. et al. // J. B-iol. Inorg. Chem. 2014. V. 19. № 2. P. 191.
Dorazio S.J., Morrow J.R. // Eur. J. Inorg. Chem. 2012. V. 2012. № 12. P. 2006.
Ferrauto G., Castelli D.D., Terreno E. et al. // Magn. Reson. Med. 2013. V. 69. № 6. P. 1703.
Jeon I.-R., Park J.G., Haney C.R. et al. // Chem. Sci. 2014. V. 5. № 6. P. 2461.
Wang H., Wong A., Lewis L.C. et al. // Inorg. Chem. 2020. V. 59. № 23. P. 17712.
Thorarinsdottir A.E., Du K., Collins J.H. et al. // J. Am. Chem. Soc. 2017. V. 139. № 44. P. 15836.
Bond C.J., Cineus R., Nazarenko A.Y. et al. // Dalton Trans. 2020. V. 49. № 2. P. 279.
Morrow J.R., Raymond J.J., Chowdhury S.I. et al. // Inorg. Chem. 2022. V. 61. № 37. P. 14487.
Tsitovich P.B., Burns P.J., McKay A.M. et al. // J. Inorg. Biochem. 2014. V. 133. P. 143.
Wang H., Jordan V.C., Ramsay I.A. et al. // J. Am. Chem. Soc. 2019. V. 141. № 14. P. 5916.
Olatunde A.O., Dorazio S.J., Spernyak J.A. et al. // J. Am. Chem. Soc. 2012. V. 134. № 45. P. 18503.
Dorazio S.J., Tsitovich P.B., Siters K.E. et al. // J. Am. Chem. Soc. 2011. V. 133. № 36. P. 14154.
Dorazio S.J., Olatunde A.O., Spernyak J.A. et al. // Chem. Commun. 2013. V. 49. № 85. P. 10025.
Botár R., Molnar E., Trencsenyi G. et al. // J. Am. Chem. Soc. 2020. V. 142. № 4. P. 1662.
Burns P.J., Cox J.M., Morrow J.R. // Inorg. Chem. 2017. V. 56. № 8. P. 4545.
Scepaniak J.J., Kang E.B., John M. et al. // Eur. J. Inorg. Chem. 2019. V. 2019. № 19. P. 2404.
Xue S.S., Pan Y., Pan W. et al. // Chem. Sci. 2022. V. 13. № 33. P. 9468.
Halcrow M.A. // Coord. Chem. Rev. 2005. V. 249. № 24. P. 2880.
Melnikova E.K., Aleshin D.Yu., Nikovskiy I.A. et al. // Crystals. 2020. V. 10. № 9. P. 793.
Sheldrick G.M. // Acta Crystallogr. A. 2008. V. 64. P. 112.
Sheldrick G., Dolomanov O.V., Bourhis L.J. et al. // J. Appl. Crystallogr. 2009. V. 42. P. 339.
Neese F., Wennmohs F., Becker U. et al. // J. Chem. Phys. 2020. V. 152. № 22. P. 224108.
Alvarez S. // Chem. Rev. 2015. V. 115. № 24. P. 13447.
Barrett S.A., Kilner C.A., Halcrow M.A. // Dalton Trans. 2011. V. 40. № 45. P. 12021.