Heteroleptic Metal-Organic Frameworks of Lanthanides (Lа, Ce, and Ho) Based on Ligands of the Anilate Type and Dicarboxylic Acids

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Resumo

New heteroleptic metal-organic frameworks of lanthanides, units of which contain anionic organic ligands of two types, are prepared by the solvothermal synthesis in N,N-dimethylformamide (DMF). The cross-linked coordination polymer [Ho2(CA)2(Bdc)·4DMF] (I) and two scaffold derivatives [La2(pQ)2(Bpdc)·4DMF] (II) and [Ce2(CA)(Bdc)2·4DMF]·2DMF (III·2DMF), where CA is chloranilic acid dianion, pQ is 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquinone dianion, Bdc is terephthalic acid dianion, and Bpdc is 4,4'-biphenyldicarboxylic acid dianion, are synthesized. The structures of compounds I, II, and III·2DMF are studied by X-ray diffraction (XRD) (CIF file CCDC nos. 2212230, 2212231, and 2212232, respectively).

Sobre autores

O. Trofimova

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: pial@iomc.ras.ru
Россия, Нижний Новгород

A. Maleeva

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: pial@iomc.ras.ru
Россия, Нижний Новгород

K. Arsen’eva

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: pial@iomc.ras.ru
Россия, Нижний Новгород

A. Klimashevskaya

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: pial@iomc.ras.ru
Россия, Нижний Новгород

A. Cherkasov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: pial@iomc.ras.ru
Россия, Нижний Новгород

A. Piskunov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Autor responsável pela correspondência
Email: pial@iomc.ras.ru
Россия, Нижний Новгород

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