Adducts of Sterically Hindered Tellurium Catecholate with N-Methylpyrrolidone

P. A. Petrov; Петров П. А.; E. A. Filippova; Филиппова Е. А.; T. S. Sukhikh; Сухих Т. С.

doi:10.31857/S0132344X24100033

Adducts of Sterically Hindered Tellurium Catecholate with N-Methylpyrrolidone

Authors: Petrov P.A.¹, Filippova E.A.¹, Sukhikh T.S.¹
Affiliations:
1. Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
Issue: Vol 50, No 10 (2024)
Pages: 661-668
Section: Articles
URL: https://journals.rcsi.science/0132-344X/article/view/273475
DOI: https://doi.org/10.31857/S0132344X24100033
EDN: https://elibrary.ru/LPWAYK
ID: 273475

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Abstract

The formation of adducts of tellurium(IV) 3,6-di-tert-butyl catecholate (Te(Cat³⁶)₂) with N-methylpyrrolidone (NMP) is studied. The crystallization from a CH₂Cl₂–NMP–aromatic hydrocarbon mixture is found to result in the formation of dimeric complexes [{Te(Cat³⁶)₂}₂(μ-NMP)(μ-arene)] (arene = C₆H₆, C₇H₈), whereas mononuclear [Te(Cat³⁶)₂(NMP)₂] is formed from a CH₂Cl₂–NMP–alkane mixture. The formation of the adducts with aromatic hydrocarbons indicates a possibility of using the tellurium complexes for the separation of hydrocarbon mixtures, including an industrially important benzene–cyclohexane mixture.

Keywords

tellurium, quinones, XRD, N-methylpyrrolidone, NMR

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