New stannandiamines comprising photoactive fragments

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The reactions of dibutyltin dichloride with potassium amides KNH-pap, KNH-4pbt, and KNH-2pbt (pap = 4-(phenylazo)phenyl; 4pbt = 1,3-benzothiazol-2-yl-4-phenyl; 2pbt = 1,3-benzothiazol-2-yl-2-phenyl) were studied. It was found that in the case of KNH-pap and KNH-4pbt, the only products formed were stannanediamines nBu2Sn(NH-pap)2 (I) and nBu2Sn(NH-4pbt)2 (II). However, in the case of KNH-2pbt, an inseparable mixture of stannanediamine nBu2Sn(NH-2pbt)2 ( III) and cyclodistannadiazane [nBu2Sn(N-2pbt)]2 (IV) was obtained. The molecular structures of compounds I–IV were determined by single-crystal X-ray diffraction (SCXRD) analysis of the crystalline phases I · 0.5C7H8, II · 0.5THF, III, and IV (CCDC No 2367378 (I · 0.5C7H8), 2367379 (II · 0.5THF), 2367380 (III), and 2367378 (IV)).

About the authors

A. G. Demkin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: konch@niic.nsc.ru
Novosibirsk, Russia

E. P. Latushko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk National Research State University

Email: konch@niic.nsc.ru
Novosibirsk, Russia; Novosibirsk, Russia

B. Y. Savkov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: konch@niic.nsc.ru
Novosibirsk, Russia

T. S. Sukhikh

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: konch@niic.nsc.ru
Novosibirsk, Russia

S. N. Konchenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: konch@niic.nsc.ru
Novosibirsk, Russia

References

  1. Liu B., Li L., Sun G. et al. // Macromolecules. 2014. V. 47. № 15. P. 4971.
  2. Liu B., Sun G., Li S. et al. // Organometallics. 2015. V. 34. № 16. P. 4063.
  3. Lu D., Yu J.K., Kuo T. et al. // Angew. Chemie Int. Ed. 2011. V. 50. № 33. P. 7611.
  4. Zhu X., Guo D., Zhang Y. et al. // Organometallics. 2020. V. 39. № 24. P. 4584.
  5. Zhu X., Guo D., Zhang Y. et al. // Organometallics. 2009. V. 28. № 13. P. 3882.
  6. Tazelaar C.G.J., Bambirra S., van Leusen D. et al. // Organometallics. 2004. V. 23. № 5. P. 936.
  7. Mironova O.A., Lashchenko D.I., Ryadun A.A. et al. // New J. Chem. 2022. V. 46. № 5. P. 2351.
  8. Баширов Д.А., Сухих Т.С., Конченко С.Н. // Журн. неорган. химии. 2023. Т. 68. № 9. С. 1211 (Bashirov D.A., Sukhikh T.S., Konchenko S.N // Russ. J. Inorg. Chem. 2023. V. 68. № 9. P. 1211). https://doi.org/10.31857/S0044457X23601025
  9. Mironova O.A., Ryadun A.A., Sukhikh T.S. et al. // New J. Chem. 2023. Vol. 47. № 7. P. 3406.
  10. Mironova O. A., Ryadun A.A., Pushkarevsky N.A. et al. // J. Struct. Chem. 2024. V. 65. № 2. P. 399.
  11. Jones K., Lappert M.F. // J. Chem. Soc. 1965. P. 1944.
  12. Дергунов Ю.И., Герега В.Ф., Дьячковская О.С. // Успехи химии 1977. Т. 46. № 12. С. 2139 (Dergunov Y.I., Gerega V.F., D’yachkovskaya O.S. // Russ. Chem. Rev. 1977. Vol. 46. № 12. P. 1132). https://doi.org/10.1070/RC1977v046n12ABEH002191
  13. Baz F.El, Riviere-Baudet M., Chazalettte C. et al. // Phosphorus. Sulfur. Silicon Relat. Elem. 2000. V. 163. № 1. P. 121.
  14. Padělková Z., Havlík A., Švec P.et al. // J. Organomet. Chem. 2010. V. 695. № 24. P. 2651.
  15. Afonin M.Y., Martynenko P.A., Kolybalov D.S. et al. // Inorg. Chem. 2024. V. 63. № 1. P. 369.
  16. Bandara H.M.D., Burdette S.C. // Chem. Soc. Rev. 2012. V. 41. № 5. P. 1809.
  17. Joshi N.K., Fuyuki M., Wada A. // J. Phys. Chem. B. 2014. V. 118. № 7. P. 1891–1899.
  18. Gordon A.J., Ford R.A. The chemist’s companion: a handbook of practical data, techniques and references. New York, 1973, 560 p.
  19. Zhang J., Guo W. // Chem. Commun. 2014. V. 50. № 32. P. 4214.
  20. Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. № 1. P. 3.
  21. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. № 1. P. 3.
  22. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. № 2. P. 339.
  23. Diemer S., Noth H., Polborn K. et al. // Chem. Ber. 1992. V. 125. № 2. P. 389.
  24. Junk P.C., Leary S.G. // Inorg. Chim. Acta. 2004. V. 357. № 7. P. 2195.
  25. Schulz A., Thomas M., Villinger A. // Daltщт Trans. 2019. V. 48. № 1. P. 125.
  26. Sawyer J.F. // Acta Crystallogr. C. 1988. V. 44. № 4. P. 633.
  27. Schneider J., Krebs K.M., Freitag S. et al. // Chem. Eur. J. 2016. V. 22. № 28. P. 9812.
  28. Fischer M., Roy M.M.D., Wales L.L. et al. // Angew. Chem. Int. Ed. 2022. V. 61. № 48. Art. e2022116.
  29. Raharinirina A., Boese R., Schmid G. // J. Organomet. Chem. 1990. V. 395. № 1. P. 39.
  30. Lichtscheidl A.G., Janicke M.T., Scott B.L. et al. // Dalton Trans. 2015. V. 4. № 36. P. 16156.
  31. Fooken U., Saak W., Weidenbruch M. // J. Organomet. Chem. 1999. V. 579. № 1–2. P. 280.
  32. Janiak C. // Dalton. Trans. 2000. № 21. P. 3885.
  33. Piskunov A.V., Aivaz’yan I.A., Fukin G.K. et al. // Inorg. Chem. Commun. 2006. V. 9. № 6. P. 612.
  34. Ладо A.В., Пискунов А.В., Черкасов В.К. и др. // Коорд. химия. 2006. Т. 32. № 3. С. 181 (Lado A.V., Piskunov A.V., Cherkasov V.K. et al. // Russ. J. Coord. Chem. 2006. V. 32. № 3. P. 173). https://doi.org/10.1134/S1070328406030031
  35. Lado A.V., Poddel’sky A.I., Piskunov A.V. et al. // Inorg. Chim. Acta. 2005. V. 358. № 15. P. 4443.
  36. Seifert T., Storch W., Vosteen M. // Eur. J. Inorg. Chem. 1998. V. 1998. № 9. P. 1343.
  37. Fuentes N., Martín-Lasanta A., Álvarez de Cienfuegos L. et al. // Nanoscale. 2011. V. 3. № 10. P. 4003.
  38. Khisamov R.M., Ryadun A.A., Sukhikh T.S. et al. // Mol. Syst. Des. Eng. 2021. V. 6. № 12. P. 1056.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2025 Russian Academy of Sciences

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).