Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

A procedure for the synthesis of the new ditopic ligand combining in the structure 1- and 5-substituted tetrazolyl cycles, 5-(2-(1H-tetrazol-1-yl)phenyl)-1H-tetrazole (HL), is developed. The coordination compounds of Co(II) and Cu(II) halides [Co(HL)2Cl2], [Cu(HL)2Cl2], [Cu(HL)2Br2], and [CuL2(H2O)]n based on ligand HL are synthesized. The complexes are studied by elemental analysis, diffuse reflectance spectroscopy, IR spectroscopy, X-ray diffraction (XRD), and static magnetic susceptibility. The crystal structure of the molecular coordination polymer [CuL2(H2O)]n is determined by XRD (CIF file CCDC no. 2127210). The temperature and field dependences of the magnetization show that the magnetic properties of the synthesized Cu(II) complexes are due to exchange interactions in one-dimensional chains of the copper ions (S = 1/2). For complex [Cu(HL)2Br2], the parameters are shifted toward the enhancement of the antiferromagnetic interaction compared to the analog containing the chloride ion.

About the authors

L. G. Lavrenova

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: ludm@niic.nsc.ru
Россия, Новосибирск

E. Yu. Grigor’ev

Institute of Physicochemical Problems, Belarussian State University, Minsk, Belarus

Email: ludm@niic.nsc.ru
Беларусь, Минск

V. Yu. Komarov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: ludm@niic.nsc.ru
Россия, Новосибирск

L. A. Glinskaya

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: ludm@niic.nsc.ru
Россия, Новосибирск

A. N. Lavrov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia; Novosibirsk National Research State University, Novosibirsk, Russia

Email: ludm@niic.nsc.ru
Россия, Новосибирск; Россия, Новосибирск

Yu. V. Grigor’ev

Institute of Physicochemical Problems, Belarussian State University, Minsk, Belarus

Author for correspondence.
Email: ludm@niic.nsc.ru
Беларусь, Минск

References

  1. Yang G.W., Zhang Y.T., Wu Q. et al. // Inorg. Chim. Acta. 2016. V. 450. P. 364.
  2. Wright P.J., Kolanowski J.L., Filipek W.K. et al. // Eur. J. Inorg. Chem. 2017. P. 5260.
  3. Kaleeswaran P., Azath I.A., Tharmaraj V. et al. // ChemPlusChem. 2014. V. 79. P. 1361.
  4. Xing G., Zhang Y., Cao X. // J. Mol. Struct. 2017. V. 1146. P. 793.
  5. Nasani R., Saha M., Mobin S.M. et al. // Dalton Trans. 2014. V. 43. P. 9944.
  6. Wang F., Zhang J., Yu R. et al. // CrystEngComm. 2010. V. 12. P. 671.
  7. Tao P., Zhang Y., Wang J. et al. // J. Mater. Chem. C. 2017. V. 5. P. 9306.
  8. Umamahesh B., Karthikeyan N.S., Sathiyanarayanan K.I. et al. // J. Mater. Chem. C. 2016. V. 4. P. 10053.
  9. Colombo A., Dragonetti C., Magni M. et al. // Dalton Trans. 2015. V. 44. P. 11788.
  10. Xu R.-J., Fu D.-W., Dai J. et al. // Inorg. Chem. Commun. 2011. V. 14. P. 1093.
  11. Гапоник П.Н., Войтехович С.В., Ивашкевич О.А. // Успехи химии. 2006. Т. 75. № 6. С. 569 (Gaponik P.N., Voitekhovich S.V., Ivashkevich O.A. // Russ. Chem. Rev. 2006. V. 75. № 6. P. 507). https://doi.org/10.1070/RC2006v075n06ABEH003601
  12. Zhao H., Qu Z.-R., Ye H.-Y. et al. // Chem Soc. Rev. 2008. V. 37. P. 84.
  13. Ouellette W., Jones S., Zubieta J. // CrystEngComm. 2011. V. 13. P. 4457.
  14. Kang X.-M., Tang M.-H., Yang G.-L. et al. // Coord. Chem. Rev. 2020. V. 422. P. 213424.
  15. Chi Y., Tong B., Chou P.-T. // Coord. Chem. Rev. 2014. V. 281. P. 1.
  16. Massi M., Stagni S., Ogden M.I. // Coord. Chem. Rev. 2017. V. 375. P. 164.
  17. Шакирова О.Г., Лавренова Л.Г., Куратьева Н.В. и др. // Журн. структур. химии. 2017. Т. 58. № 5. С. 958 (Shakirova O.G., Lavrenova L.G., Kuratieva N.V. et al. // J. Struct. Chem. 2017. V. 58. № 5. P. 919). https://doi.org/10.1134/S0022476617050092
  18. Grigorieva I.M., Serebryanskaya T.V., Grigoriev Y.V. et al. // Polyhedron. 2018. V. 151. P. 74.
  19. Voitekhovich S.V., Grigoriev Yu.V., Lyakhov A.S. et al. // Polyhedron. 2020. V. 176. P. 114299.
  20. Ivanova A.D., Grigoriev Yu.V., Komarov V.Yu. et al. // Polyhedron. 2020. V. 189. P. 114750.
  21. Ivanova A.D., Grigoriev Yu.V., Komarov V.Yu. et al. // Inorg. Chim. Acta. 2021. V. 524. P. 120452.
  22. Voitekhovich S.V., Grigoriev Yu.V., Lyakhov A.S. et al. // Polyhedron. 2021. V. 194. P. 114907.
  23. Bruker APEX3 Software Suite (APEX3 v.2019.1-0, SADABS v.2016/2, SAINT v.8.40a), Madison (WI, USA): Bruker Nonius (2003–2004), Bruker AXS (2005–2018), Bruker Nano (2019).
  24. Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3.
  25. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
  26. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Ap-pl. Crystallogr. 2009. V. 42. P. 339.
  27. Butler R.N. // Comprehensive Heterocyclic Chemistry / Eds. Katritzky A.R., Rees C.W. Oxford.: Pergamon Press, 1984. V. 5. P. 791.
  28. Gaponik P.N., Karavai V.P., Grigoriev Yu.V. // Chem. Heterocycl. Compd. 1985. V. 21. № 11. P. 1255.
  29. Григорьев Ю.В., Войтехович С.В., Каравай В.П. и др. // Химия гетероцикл. соед. 2017. Т. 53. № 6–7. С. 670 (Grigoriev Yu.V., Voitekhovich S.V., Karavai V.P. et al. // Chem. Heterocycl. Compd. 2017. V. 53. № 6–7. P. 670). https://doi.org/10.1007/s10593-017-2108-7
  30. Boča R. // Coord. Chem. Rev. 2004. V. 248. P. 757.
  31. Bonner J.C., Fisher M.E. // Phys. Rev. 1964. V. 135. P. A640.

Supplementary files

Supplementary Files
Action
1. JATS XML
2.

Download (11KB)
3.

Download (63KB)
4.

Download (416KB)
5.

Download (335KB)
6.

Download (559KB)
7.

Download (160KB)
8.

Download (150KB)
9.

Download (143KB)
10.

Download (148KB)


This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies