Гидрирование фурфурола, 5-гидроксиметилфурфурола и левулиновой кислоты в присутствии Pd катализатора, нанесенного на мезопористый цирконосиликат

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Abstract

Синтезирован катализатор на основе наночастиц Pd, нанесенных на мезопористый цирконосиликат. Катализатор испытан в гидрировании фурфурола, 5-гидроксиметилфурфурола и левулиновой кислоты при температурах 150–250°С и давлении водорода 5 МПа. Установлено, что температура процесса оказывает существенное влияние на распределение продуктов гидрирования фурфурола и 5-гидроксиметилфурфурола. Гидрирование левулиновой кислоты проходит селективно с образованием γ-валеролактона, конверсия значительно возрастает с ростом температуры.

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About the authors

Екатерина Алексеевна Ролдугина

Московский государственный университет им. М. В. Ломоносова

Author for correspondence.
Email: maxbv04@gmail.com
ORCID iD: 0000-0002-9194-1097

Химический факультет, к.х.н.

Russian Federation, 119991, ГСП-1, г. Москва, Ленинские горы, д. 1, стр. 3

Максим Павлович Бороноев

Московский государственный университет им. М. В. Ломоносова

Email: maxbv04@gmail.com
ORCID iD: 0000-0001-6129-598X

Химический факультет, к.х.н.

Russian Federation, 119991, ГСП-1, г. Москва, Ленинские горы, д. 1, стр. 3

Искандер Ильгизович Шакиров

Московский государственный университет им. М. В. Ломоносова

Email: maxbv04@gmail.com
ORCID iD: 0000-0003-2029-693X
Russian Federation, 119991, ГСП-1, г. Москва, Ленинские горы, д. 1, стр. 3

Юлия Сергеевна Кардашева

Московский государственный университет им. М. В. Ломоносова

Email: maxbv04@gmail.com
ORCID iD: 0000-0002-6580-1082

Химический факультет, к.х.н.

Russian Federation, 119991, ГСП-1, г. Москва, Ленинские горы, д. 1, стр. 3

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Supplementary files

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1. JATS XML
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2. Fig. 1. Nitrogen adsorption–desorption isotherms and pore size distribution of mesoporous zirconosilicate and Pd catalyst supported on mesoporous zirconosilicate.

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3. Fig. 2. Spectra of temperature-programmed ammonia desorption of mesoporous zirconosilicate and Pd catalyst supported on mesoporous zirconosilicate.

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4. Fig. 3. X-ray diffraction pattern (a) and small-angle scattering pattern (b) of a Pd catalyst supported on mesoporous zirconosilicate.

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5. Fig. 4. Microphotographs (a, b) of a Pd catalyst supported on mesoporous zirconosilicate, and a diagram of the size distribution of Pd nanoparticles (c).

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