Heterogeneous Phosphine-Containing Hydroformylation Catalysts Based on Modified Porous Organic Framework

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Abstract

A series of heterogeneous phosphine-containing rhodium hydroformylation catalysts based on porous aromatic frameworks (PAFs) were prepared. The catalysts PAF30-MDEA-TPPTS-Rh (TPPTS is trisodium triphenylphosphine-3,3',3''-trisulfonate, MDEA is methyldiethanolamine fragment) and PAF-30-Im-TPPTS-Rh (Im is imidazole fragment) showed the highest stability in repeated use in 1-hexene hydroformylation. The catalyst PAF-30-MDEA-TPPTS-Rh before and after use in hydroformylation was characterized by elemental C,N,H,S analysis, inductively coupled plasma atomic absorption spectroscopy, low-temperature nitrogen adsorption–desorption, transmission electron microscopy, IR spectroscopy, and X-ray photoelectron spectroscopy. The effect of temperature, pressure, and solvent on the course of hydroformylation in the presence of PAF-30-MDEA-TPPTS-Rh was studied. The catalyst is active in hydroformylation of a series of unsaturated compounds, including functionalized substrates and olefins with internal double bond.

About the authors

Khanlin' Van

Department of Chemistry, Moscow State University

Email: acjournal.nauka.nw@yandex.ru
119991, Moscow, Russia

M. V. Nenasheva

Department of Chemistry, Moscow State University

Email: acjournal.nauka.nw@yandex.ru
119991, Moscow, Russia

L. A. Kulikov

Department of Chemistry, Moscow State University

Email: acjournal.nauka.nw@yandex.ru
119991, Moscow, Russia

A. V. Akopyan

Department of Chemistry, Moscow State University

Email: acjournal.nauka.nw@yandex.ru
119991, Moscow, Russia

D. N. Gorbunov

Department of Chemistry, Moscow State University

Author for correspondence.
Email: acjournal.nauka.nw@yandex.ru
119991, Moscow, Russia

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