Esters of Inulin and Tall Oil Fatty Acids

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The possibility of obtaining polysaccharide esters based on large-scale products of plant origin: inulin and tall oil fatty acids, was studied. Carbohydrate esters of the biopolymer inulin and higher unsaturated acids were synthesized by acylation with acid chlorides under various conditions: in a water–chloroform mixture in the presence of sodium hydroxide and sodium salts of tall oil fatty acids, as well as in a pyridine–1,4-dioxane mixture. The yield of polysaccharide esters was 67–82%, the maximum yield was detected during the acylation of inulin in the pyridine–1,4-dioxane system

About the authors

A. V. Kurzin

St. Petersburg State University of Industrial Technologies and Design

Email: acjournal.nauka.nw@yandex.ru
191186, St. Petersburg, Russia

A. N. Evdokimov

St. Petersburg State University of Industrial Technologies and Design

Email: acjournal.nauka.nw@yandex.ru
191186, St. Petersburg, Russia

N. S. Il'ina

ITMO University

Author for correspondence.
Email: acjournal.nauka.nw@yandex.ru
197101, St. Petersburg, Russia

References

  1. Ahmad M. U., Xu X. Polar lipids: Biology, chemistry, and technology. Urbana: AOCS Press, 2015. P. 215-243. https://doi.org/10.1016/C2015-0-02381-4
  2. Tracy P., Dasgupta D., More S. Challenges and opportunities for production of C5 sugar fatty acid esters (SFAEs) from renewable resources // Ind. Crops Prod. 2023. V. 193. ID 116170. https://doi.org/10.1016/j.indcrop.2022.116170
  3. Bhanja A., Sutar P. P., Mishra M. Inulin-A Polysaccharide: Review on its functional and prebiotic efficacy //j. Food Biochem. 2022. V. 46. N 12. e14386. https://doi.org/10.1111/jfbc.14386
  4. Mensink M. A., Frijlink H. W., van der Voort Maarschalk K., Hinrichs W. L. J. Inulin, a flexible oligosaccharide I: Review of its physicochemical characteristics // Carbohydr. Polym. 2015. V. 130. P. 405-419. https://doi.org/10.1016/j.carbpol.2015.05.026
  5. Stevens C. V., Meriggi A., Booten K. Chemical modification of inulin, a valuable renewable resource, and its industrial applications // Biomacromolecules. 2001. V. 2. N 1. P. 1-16. https://doi.org/10.1021/bm005642t
  6. Головин А. И., Трофимов А. Н., Узлов Г. А., Жукова И. П., Киприанов А. И., Прохорчук Т. И., Ковалев В. Е. Лесохимические продукты сульфатцеллюлозного производства. М.: Лесн. пром-сть, 1988. С. 64-68.
  7. Evdokimov A. N., Kurzin A. V., Popova L. M., Franchuk V. B. Purification of tall oil fatty acids by removing of stilbenes // Eur. J. Wood Prod. 2021. V. 79. N 4. P. 1027-1029. https://doi.org/10.1007/s00107-021-01663-9
  8. Wang S.-F., Furuno T., Cheng Z. Synthesis of new amino acid-type amphoteric surfactants from tall oil fatty acid //j. Wood Sci. 2001. V. 47. N 6. P. 470-475. https://doi.org/10.1007/BF00767900
  9. Торлопов М. А., Удоратина Е. В., Кучин А. В. Синтез эфиров инулина и фенолкарбоновых кислот // ЖОрХ. 2013. Т. 49. № 5. С. 719-723. EDN: PZEQTP
  10. Курзин А. В., Евдокимов А. Н., Павлова О. С., Антипина В. Б. Эфиры амилозы, целлюлозы и жирных кислот таллового масла // ЖПХ. 2008. Т. 81. № 12. С. 2068-2069. EDN: KFSREZ

Copyright (c) 2023 Russian Academy of Sciences

This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies