Bisisocyanide cyclometallated platinum(II) complexes: synthesis, structure, photophysical properties, and mechanochromic behavior
- Authors: Katkova S.A1, Sokolova E.V1, Kinzhalov M.A1
-
Affiliations:
- St. Petersburg State University
- Issue: Vol 93, No 1 (2023)
- Pages: 113-125
- Section: Articles
- URL: https://journals.rcsi.science/0044-460X/article/view/144987
- DOI: https://doi.org/10.31857/S0044460X23010134
- EDN: https://elibrary.ru/OZPAUN
- ID: 144987
Cite item
Abstract
A series of cyclometallated platinum(II) complexes [Pt(ppy){CNAr}2]X with two isocyanide ligands (Hppy = 2-phenylpyridine, Ar = C6H2-2,4,6-Me3, C6H3-2-Cl-6-Me , C6H3-2,6-Cl2, C6H4-4-NMe2, C6H4-4-Me, C6H4 4-Cl, C6H4-4-Br, C6H4-4-I, C6H4-4-CF3, C6H4-3-CF3; X = BF4, OTf) was synthesized by the reaction of the [{Pt(ppy)Cl}2] dimer with isocyanides (yield 52-70%). The structure of the resulting complexes was determined using mass spectrometry, 1H, 13C{1H}, 195Pt{1H}, 1H-1H COSY, 1H-1H NOESY, 1H-13C HSQC, and 1H-13C HMBC NMR spectroscopy in solution and solid-state CP/MAS 13C and 195Pt NMR spectroscopy, IR spectroscopy and X-ray diffraction analysis in the solid phase. The photophysical properties of the obtained complexes in the solid phase and the mechanochromic luminescence behavior were studied. In the solid phase, all synthesized compounds phosphoresce in the green or orange range of visible light, while photoluminescence quantum yields reach 26%. Green phosphors exhibit a reversible mechanochromic luminescence change achieved by mechanical grinding (green to orange) and solvent adsorption (orange to green).
Keywords
About the authors
S. A Katkova
St. Petersburg State University
Email: s.katkova@spbu.ru
E. V Sokolova
St. Petersburg State University
M. A Kinzhalov
St. Petersburg State University
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