Heteroleptic Anionic Cobalt(II) Pivalate Complex with a Bridging Trimethylsiloxy Ligand: Synthesis, Structure, and Formation Mechanism
- 作者: Petrov P.1, Nikolaevskii S.2, Yambulatov D.2, Starikova A.3, Sukhikh T.1, Kiskin M.2, Sokolov M.1, Eremenko I.2
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隶属关系:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Research Institute of Physical and Organic Chemistry, Southern Federal University
- 期: 卷 68, 编号 9 (2023)
- 页面: 1255-1264
- 栏目: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
- URL: https://journals.rcsi.science/0044-457X/article/view/136492
- DOI: https://doi.org/10.31857/S0044457X23600998
- EDN: https://elibrary.ru/YFRWMW
- ID: 136492
如何引用文章
详细
The heteroleptic anionic complex (IPrPhH)[Co2(μ-Piv)2(μ-OSiMe3)(Piv)2] (I) was synthesized through the reaction of cobalt pivalate [Co(Piv)2]n with 1,3-bis(2,6-diisopropylphenyl)-2-phenylimidazolium iodide ([IPrPhH]I) and KN(SiMe3)2 and studied by X-ray diffraction both in the solvate-free form and in the form of solvate with pentane (I⋅0.75C5H12) (CCDC 2257678–2257679). Modeling of the probable mechanism of formation of complex I and evaluation of exchange coupling between paramagnetic centers in it were carried out by density functional theory method.
作者简介
P. Petrov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: panah@niic.nsc.ru
630090, Novosibirsk, Russia
S. Nikolaevskii
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: sanikol@igic.ras.ru
119991, Moscow, Russia
D. Yambulatov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: sanikol@igic.ras.ru
119991, Moscow, Russia
A. Starikova
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: sanikol@igic.ras.ru
344090, Rostov-on-Don, Russia
T. Sukhikh
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: sanikol@igic.ras.ru
630090, Novosibirsk, Russia
M. Kiskin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: sanikol@igic.ras.ru
119991, Moscow, Russia
M. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: sanikol@igic.ras.ru
630090, Novosibirsk, Russia
I. Eremenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: sanikol@igic.ras.ru
119991, Moscow, Russia
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