Heteroleptic Anionic Cobalt(II) Pivalate Complex with a Bridging Trimethylsiloxy Ligand: Synthesis, Structure, and Formation Mechanism

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Abstract

The heteroleptic anionic complex (IPrPhH)[Co2(μ-Piv)2(μ-OSiMe3)(Piv)2] (I) was synthesized through the reaction of cobalt pivalate [Co(Piv)2]n with 1,3-bis(2,6-diisopropylphenyl)-2-phenylimidazolium iodide ([IPrPhH]I) and KN(SiMe3)2 and studied by X-ray diffraction both in the solvate-free form and in the form of solvate with pentane (I⋅0.75C5H12) (CCDC 2257678–2257679). Modeling of the probable mechanism of formation of complex I and evaluation of exchange coupling between paramagnetic centers in it were carried out by density functional theory method.

About the authors

P. A. Petrov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: panah@niic.nsc.ru
630090, Novosibirsk, Russia

S. A. Nikolaevskii

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: sanikol@igic.ras.ru
119991, Moscow, Russia

D. S. Yambulatov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: sanikol@igic.ras.ru
119991, Moscow, Russia

A. A. Starikova

Research Institute of Physical and Organic Chemistry, Southern Federal University

Email: sanikol@igic.ras.ru
344090, Rostov-on-Don, Russia

T. S. Sukhikh

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: sanikol@igic.ras.ru
630090, Novosibirsk, Russia

M. A. Kiskin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: sanikol@igic.ras.ru
119991, Moscow, Russia

M. N. Sokolov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: sanikol@igic.ras.ru
630090, Novosibirsk, Russia

I. L. Eremenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: sanikol@igic.ras.ru
119991, Moscow, Russia

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Copyright (c) 2023 П.А. Петров, С.А. Николаевский, Д.С. Ямбулатов, А.А. Старикова, Т.С. Сухих, М.А. Кискин, М.Н. Соколов, И.Л. Еременко

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