Features of Copper(I) Complexation with Benzimidazole Derivatives in the Presence of the closo-Dodecaborate Anion

S. E. Nikiforova; Никифорова С. Е.; A. S. Kubasov; Кубасов А. С.; O. N. Belousova; Белоусова О. Н.; V. V. Avdeeva; Авдеева В. В.; E. A. Malinina; Малинина Е. А.; N. T. Kuznetsov; Кузнецов Н. Т.

doi:10.31857/S0044457X2260219X

Features of Copper(I) Complexation with Benzimidazole Derivatives in the Presence of the closo-Dodecaborate Anion

作者: Nikiforova S.¹, Kubasov A.¹, Belousova O.¹, Avdeeva V.¹, Malinina E.¹, Kuznetsov N.¹
隶属关系:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
期: 卷 68, 编号 6 (2023)
页面: 832-841
栏目: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://journals.rcsi.science/0044-457X/article/view/136490
DOI: https://doi.org/10.31857/S0044457X2260219X
EDN: https://elibrary.ru/UEQTWF
ID: 136490

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详细

The process of copper(I) complexation with organic ligands as luminophores 1-(1-methylbenzimidazol-2-yl)-N-phenylmethanimine (L1), 1-ethyl-2-(4-methoxyphenyl)azobenzimidazole (L2), and 1-(1-benzylbenzimidazol-2-yl)-N-cyclohexylmethanimine (L3) in the presence of the closo-dodecaborate anion [B12H12]2– has been studied. It has been shown that in acetonitrile, a redox reaction proceeds to form copper(II) tris-chelate complexes [CuIIL3][B12H12]. Using diiodomethane as a solvent, we have succeeded in stabilizing copper in the +1 oxidation state; as a result, mixed-ligand binuclear complexes [CuI2L2(μ-I)2] containing no boron cluster anion have been isolated. The structures of complexes [CuII(L1)3][B12H12] and [CuI2(L3)2(μ‑I)2] have been determined by X-ray diffraction.

关键词

coordination compounds, boron cluster anions, redox reactions, copper(II)

参考

Kumaravel G., Raman N. // Mater. Sci. Eng. C. 2017. V. 70. P. 184. https://doi.org/10.1016/j.msec.2016.08.069
Mahmood K., Hashmi W., Ismail H. et al. // Polyhedron. 2018. V. 157. P. 326. https://doi.org/10.1016/j.poly.2018.10.020
Rajarajeswari C., Loganathan R., Palaniandavar M. et al. // Dalton Trans. 2013. V. 42. P. 8347. https://doi.org/10.1039/C3DT32992E
Galal S., Hegab K., Hashem A., Youssef N. // Eur. J. Med. Chem. 2010. V. 45. P. 5685. https://doi.org/10.1016/j.ejmech.2010.09.023
Gupta M., Mathur P., Butcher R. // Inorg. Chem. 2001. V. 40. P. 878. https://doi.org/10.1021/ic000313v
Puchoňová M., Švorec J., Švorc Ľ. et al. // Inorg. Chim. Acta. 2017. V. 455. P. 298. https://doi.org/10.1016/j.ica.2016.10.034
Lavrenova L.G., Kuz’menko T.A., Ivanova A.D. et al. // New J. Chem. 2017. V. 41. P. 4341. https://doi.org/10.1039/C7NJ00533D
Иванова А.Д., Кузьменко Т.А., Смоленцев А.И. и др. // Журн. коорд. химии. 2021. Т. 47. С. 689.
Xiao B., Hou H., Fan Y.J. // J. Organomet. Chem. 2007. V. 692. P. 2014. https://doi.org/10.1016/j.jorganchem.2007.01.010
Chen W., Xi C., Wu Y. // J. Organomet. Chem. 2007. V. 692. P. 4381. https://doi.org/10.1016/j.jorganchem.2007.07.006
Hao P., Zhang S., Sun W.-H. et al. // Organometallics. 2007. V. 26. P. 2439. https://doi.org/10.1021/om070049e
Haneda S., Gan Z., Eda K., Hayashi M. // Organometallics. 2007. V. 26. P. 6551. https://doi.org/10.1021/om7008843
Sun W.-H., Hao P., Znang S. et al. // Organometallics. 2007. V. 26. P. 2720. https://doi.org/10.1021/om0700819
Korolenko S.E., Zhuravlev K.P., Tsaryk V.I. et al. // J. Lumin. 2021. V. 237. P. 118156. https://doi.org/10.1016/j.jlumin.2021.118156
Yang B.B., Zhao F., Xu S.X., He H.F. // Chin. J. Inorg. Chem. 2019. V. 35. P. 1020. https://doi.org/10.11862/CJIC.2019.129
Wu T.-C., Zhao F.-Z., Hu Q.-L. et al. // Appl. Organomet. Chem. 2020. V. 34. P. e5691. https://doi.org/10.1002/aoc.5691
Huang T.-H., Hu Q.-L., Zhao F.-Z. et al. // J. Lumin. 2020. V. 227. P. 117530. https://doi.org/10.1016/j.jlumin.2020.117530
Zi X., Liu C., Lu W. et al. // Z. Anorg. Allg. Chem. 2021. V. 647. P. 1. https://doi.org/10.1002/zaac.202100238
Huang T.-H., Luo C., Zheng D. // Org. Electron. 2021. V. 97. P. 106273. https://doi.org/10.1016/j.orgel.2021.106273
Song Y.-L., Jiao B.-J., Liu C.-M. et al. // Inorg. Chem. Commun. 2019. P. 107689. https://doi.org/10.1016/j.inoche.2019.107689
Авдеева В.В., Дзиова А.Э., Полякова И.Н. и др. // Журн. неорган. химии. 2013. Т. 58. С. 746.
Avdeeva V.V., Dziova A.E., Polyakova I.N. et al. // Inorg. Chim. Acta. 2015. V. 430. P. 74. https://doi.org/10.1016/j.ica.2015.02.029
Кочнев В.К., Авдеева В.В., Малинина Е.А., Кузнецов Н.Т. // Журн. неорган. химии. 2014. Т. 59. С. 1512.
Korolenko S.E., Malinina E.A., Avdeeva V.V. et al. // Polyhedron. 2021. V. 194. P. 114902. https://doi.org/10.1016/j.poly.2020.114902
Nikiforova S.E., Kubasov A.S., Goeva L.V. et al. // Polyhedron. 2022. V. 226. P. 116108. https://doi.org/10.1016/j.poly.2022.116108
Korolenko S.E., Kubasov A.S., Khan N.A. et al. // J. Cluster Sci. 2022. https://doi.org/10.1007/s10876-022-02263-0
Greenwood N.N., Morris J.H. // Proc. Chem. Soc. 1963. V. 11. P. 338.
Авдеева В.В., Полякова И.В., Гоева Л.В. и др. // Журн. неорган. химии. 2015. Т. 60. С. 901.
Bruker, SAINT, Bruker AXS Inc., Madison, WI, 2018.
Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D. // J. Appl. Crystallogr. 2015. V. 48. № 1. P. 3. https://doi.org/10.1107/S1600576714022985
Sheldrick G.M. // Acta Crystallogr., Sect. C: Struct. Chem. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. P. 339. https://doi.org/10.1107/S0021889808042726
Korolenko S.E., Malinina E.A., Avdeeva V.V. et al. // Inorg. Chim. Acta. 2022. V. 539. P.121038. https://doi.org/10.1016/j.ica.2022.121038
Малинина Е.А., Авдеева В.В., Короленко С.Е. и др. // Журн. неорган. химии. 2020. Т. 69. С. 1208.
Xu Ch., Lv Le, Zhang Zh., Liu W. // J. Cluster Sci. 2020. https://doi.org/10.1007/s10876-020-01886-5