Boron Difluoride β-Diketonates: Structure and Phosphorescence

A. G. Mirochnik; Мирочник А. Г.; E. V. Fedorenko; Федоренко Е. В.; A. V. Gerasimenko; Герасименко А. В.

doi:10.31857/S0044457X22602334

Boron Difluoride β-Diketonates: Structure and Phosphorescence

作者: Mirochnik A.¹, Fedorenko E.¹, Gerasimenko A.¹
隶属关系:
1. Institute of Chemistry, Far East Branch, Russian Academy of Sciences
期: 卷 68, 编号 6 (2023)
页面: 808-815
栏目: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://journals.rcsi.science/0044-457X/article/view/136485
DOI: https://doi.org/10.31857/S0044457X22602334
EDN: https://elibrary.ru/UFTQBB
ID: 136485

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详细

Phosphorescence data on boron difluoride β-diketonates of various structure have been systematized. Nonplanar boron difluoride molecules are characterized by the inversion of the S1 and T2 levels, which promotes efficient population of triplet levels and intense phosphorescence or delayed fluorescence of crystals. Planar molecules are characterized by a classical sequence of singlet and triplet levels and a coplanar arrangement of antiparallel molecules, which contributes to excimer delayed fluorescence.

关键词

boron chelates, structure, luminescence, delayed fluorescence, phosphorescence

参考

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