Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb–Lu)

M. V. Golikova; Голикова М. В.; A. D. Yapryntsev; Япрынцев А. Д.; Ch. Jia; Цзя Ч.; E. V. Fatyushina; Фатюшина Е. В.; A. E. Baranchikov; Баранчиков А. Е.; V. K. Ivanov; Иванов В. К.

doi:10.31857/S0044457X23601050

Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb–Lu)

Authors: Golikova M.V.¹, Yapryntsev A.D.¹, Jia C.², Fatyushina E.V.¹, Baranchikov A.E.¹, Ivanov V.K.¹^,2
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. Moscow State University
Issue: Vol 68, No 10 (2023)
Pages: 1422-1432
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://journals.rcsi.science/0044-457X/article/view/140308
DOI: https://doi.org/10.31857/S0044457X23601050
EDN: https://elibrary.ru/LMPBMN
ID: 140308

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Abstract
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Abstract

A series of yttrium subgroup rare earth elements (REE) lactates of [Ln(C3H5O3)3(H2O)2] (Ln = Tb–Lu) composition isostructural to yttrium lactate has been prepared for the first time. Synthesis of crystalline REE lactates has been performed from solutions of REE nitrates in the presence of L-lactic acid and hexamethylenetetramine. The composition and structure of the obtained compounds have been confirmed by X-ray powder diffraction, thermal, and chemical (CHN) analysis. The coordination type of lactate anions to REE cations has been determined by IR spectroscopy. Thermal decomposition of REE lactates at 800°C leads to formation of nanocrystalline (20–40 nm) REE (Y, Tb–Lu) oxides.

Keywords

homogeneous precipitation, HMT, crystals, L-lactic acid, thermal analysis

References

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