Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb–Lu)

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Resumo

A series of yttrium subgroup rare earth elements (REE) lactates of [Ln(C3H5O3)3(H2O)2] (Ln = Tb–Lu) composition isostructural to yttrium lactate has been prepared for the first time. Synthesis of crystalline REE lactates has been performed from solutions of REE nitrates in the presence of L-lactic acid and hexamethylenetetramine. The composition and structure of the obtained compounds have been confirmed by X-ray powder diffraction, thermal, and chemical (CHN) analysis. The coordination type of lactate anions to REE cations has been determined by IR spectroscopy. Thermal decomposition of REE lactates at 800°C leads to formation of nanocrystalline (20–40 nm) REE (Y, Tb–Lu) oxides.

Sobre autores

M. Golikova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yapryntsev@igic.ras.ru
Leninskii pr. 31, 119991, Moscow, Russia

A. Yapryntsev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yapryntsev@igic.ras.ru
Leninskii pr. 31, 119991, Moscow, Russia

Ch. Jia

Moscow State University

Email: yapryntsev@igic.ras.ru
119991, Moscow, Russia

E. Fatyushina

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yapryntsev@igic.ras.ru
Leninskii pr. 31, 119991, Moscow, Russia

A. Baranchikov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yapryntsev@igic.ras.ru
Leninskii pr. 31, 119991, Moscow, Russia

V. Ivanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Moscow State University

Autor responsável pela correspondência
Email: yapryntsev@igic.ras.ru
Leninskii pr. 31, 119991, Moscow, Russia; 119991, Moscow, Russia

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Declaração de direitos autorais © М.В. Голикова, А.Д. Япрынцев, Ч. Цзя, Е.В. Фатюшина, А.Е. Баранчиков, В.К. Иванов, 2023

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