Study of Crystal Structures of the [B10Cl10]2– Anion with Imidazolium Cations

A. V. Golubev; Голубев А. В.; A. S. Kubasov; Кубасов А. С.; A. Yu. Bykov; Быков А. Ю.; E. Yu. Matveev; Матвеев Е. Ю.; N. A. Sarkisov; Саркисов Н. А.; I. V. Novikov; Новиков И. В.; P. S. Starodubets; Стародубец П. С.; N. A. Romanov; Романов Н. А.; K. Yu. Zhizhin; Жижин К. Ю.; N. T. Kuznetsov; Кузнецов Н. Т.

doi:10.31857/S0044457X22602322

Study of Crystal Structures of the [B10Cl10]2– Anion with Imidazolium Cations

Authors: Golubev A.V.¹, Kubasov A.S.¹, Bykov A.Y.¹, Matveev E.Y.¹^,2, Sarkisov N.A.¹^,3, Novikov I.V.¹^,3, Starodubets P.S.⁴, Romanov N.A.⁴, Zhizhin K.Y.¹, Kuznetsov N.T.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University
3. MIREA—Russian Technological University
4. D. Mendeleev University of Chemical Technology of Russia
Issue: Vol 68, No 6 (2023)
Pages: 737-745
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://journals.rcsi.science/0044-457X/article/view/136463
DOI: https://doi.org/10.31857/S0044457X22602322
EDN: https://elibrary.ru/UFNNUM
ID: 136463

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Abstract
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Abstract

A new method for the synthesis of imidazolium salts of the perchlorinated closo-decaborate anion (RMIM)2[B10Cl10] (R = H, n-Et, n-Bu, n-C8H17) has been proposed. The synthesis of these compounds can be carried out by simple metathesis reactions between the potassium salt of the decachloro-closo-decaborate anion K2[B10Cl10] and chlorides of imidazolium derivatives. The crystal packings and intermolecular interactions in compounds (EMIM)2[B10Cl10] and (BMIM)2[B10Cl10] have been studied using X-ray diffraction and Hirshfeld surface analysis. The [B10Cl10]2– anions in the crystal lattice of these compounds are linked by a network of weak Cl···Cl interactions with a distance between chlorine atoms of 2.246–3.623 Å.

Keywords

boron clusters, perchlorinated derivatives, closo-decaborate anion, ionic liquids, X-ray diffraction

References

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