MIXED-LIGAND LUMINESCENT Cu(I) COMPLEXES BASED ON 10-(ARYL)PHENOXARSINES AND ACETONITRILE WITH A CUBANE- TYPE Cu4I4 CORE

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Abstract

Copper(I) complexes I and II of composition [L3Cu4I4(CH3CN)] (where L1 = 10-(4-tolyl)phenoxarsine L2 = 10-(4-bromophenyl)phenoxarsine) were obtained by the mechanosynthesis consisting of grinding powders of 10-(aryl)phenoxarsines and copper(I) iodide in an equimolar ratio with the addition of a small amount of acetonitrile. The complexes were characterized by mass spectrometry, elemental analysis, and 1H NMR spectroscopy. The molecular structure of complex I was confirmed by X-ray diffraction (CCDC No. 2468768 (I)). Cluster has the cubane-type geometry. All of the complexes exhibit orange emission.

About the authors

M. F. Galimova

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: milya1949@mail.ru
Kazan, Russia

A. B. Dobrynin

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Kazan, Russia

R. R. Musin

Kazan National Research Technological University

Kazan, Russia

I. E. Kolesnikov

Center for Optical and Laser Materials Research, St Petersburg University

Saint Petersburg, Russia

E. I. Musina

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Kazan, Russia

A. A. Karasik

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Kazan, Russia

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