HYDROTHERMAL SYNTHESIS OF AQUEOUS SOLS OF NANOCRYSTALLINE HAFNIUM DIOXIDE STABILIZED BY LACTIC ACID AND THEIR ENZYME-LIKE ACTIVITIES

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Abstract

A method for obtaining aqueous sols of nanocrystalline hafnium dioxide (with hydrodynamic diameter 20-35 nm) stabilised by lactic acid (lactate ions) and characterised by high colloidal stability (zeta-potential -29 mV) has been developed. The method is based on the hydrothermal treatment of a previously obtained complex compound of hafnium with lactic acid in the presence of urea at temperatures of 180 and 220 degrees Celsius for 48 and 96 h. By chemiluminescence analysis in the model reaction of luminol oxidation it was found that nanocrystalline hafnium oxide in the composition of sols exhibits dose-dependent pro-oxidant activity towards hydrogen peroxide and thus exhibits peroxidase-like properties.

About the authors

G. S Taran

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

E. D Sheichenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; International Research University Higher School of Economics

Moscow, Russia

M. A Popkov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

K. N Novoselova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; International Research University Higher School of Economics

Moscow, Russia

Yu. A Kochenkova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; International Research University Higher School of Economics

Moscow, Russia

A. D Filippova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

A. E Baranchikov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; International Research University Higher School of Economics

Email: a.baranchikov@yandex.ru
Moscow, Russia

V. K Ivanov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; International Research University Higher School of Economics

Moscow, Russia

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