Substituted Phthalimides Linked to the Cymantrenyl Moiety: Molecules with Tunable Optical and Electrochemical Properties

E. S. Kelbysheva; Келбышева Е. С.; T. V. Strelkova; Стрелкова Т. В.; M. G. Ezernitskaya; Езерницкая М. Г.; V. G. Alekseev; Алексеев В. Г.; L. N. Telegina; Телегина Л. Н.

doi:10.31857/S0044457X23600949

Substituted Phthalimides Linked to the Cymantrenyl Moiety: Molecules with Tunable Optical and Electrochemical Properties

Autores: Kelbysheva E.S.¹, Strelkova T.V.¹, Ezernitskaya M.G.¹, Alekseev V.G.², Telegina L.N.¹
Afiliações:
1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2. Faculty of Chemistry and Technology, Tver State University
Edição: Volume 68, Nº 9 (2023)
Páginas: 1265-1276
Seção: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://journals.rcsi.science/0044-457X/article/view/136495
DOI: https://doi.org/10.31857/S0044457X23600949
EDN: https://elibrary.ru/YFGNEA
ID: 136495

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Resumo

The results of investigation of the optical and electrochemical properties of substituted phthalimides linked to a cymantrenyl moiety by IR and NMR spectroscopy, UV-Vis spectroscopy, and cyclic voltammetry and also by DFT calculations are presented. It was shown that the optical, donor-acceptor, and redox properties of the organometallic phthalimides are affected by substituents in position 1 of the side chain of the cymantrene Cp and in position 4 of the phthalimide benzene ring. The reactions of dicarbonyl chelates with external ligands in the dark attest to hemilability of the Mn–O=C(imide) bond.

Palavras-chave

cymantrene, phthalimide, photochemistry, electron-withdrawing group, redox properties

Bibliografia

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